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Electrochemical Advanced Oxidation Processes for the Removal of the Drugs Paracetamol, Clofibric Acid and Chlorophene from Waters

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ȱ ȱ ȱ ȱ ȱ ȱ ȱ

UNIVERSITATȱDEȱBARCELONAȱ

FacultatȱdeȱQuímicaȱ ȱ

DEPARTAMENTȱDEȱQUÍMICAȱFÍSICAȱ

Laboratoriȱd’ElectroquímicaȱdelsȱMaterialsȱiȱdelȱMediȱAmbientȱ ȱ

ȱ ȱ ȱ ȱ

ELECTROCHEMICAL

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ADVANCED

ȱ

OXIDATION

ȱ

PROCESSES

ȱȱ

FOR

ȱ

THE

ȱ

REMOVAL

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OF

ȱ

THE

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DRUGS

ȱȱ

PARACETAMOL,

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CLOFIBRIC

ȱ

ACID

ȱ

AND

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CHLOROPHENE

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FROM

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WATERS

ȱ

ȱ ȱ

DOCTORALȱTHESISȱ

ȱ ȱ ȱ

Ignacio

ȱ

S

IRÉSȱ

S

ADORNIL

ȱ

ȱ ȱ ȱ ȱ

Barcelona,ȱnovemberȱ2006ȱ ȱ

ȱ

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R

EFERÈNCIES

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PART C

377

ȱ ȱ ȱ ȱ ȱ ȱ ȱ ȱ

12.

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REFERÈNCIES

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/

ȱ

REFERENCES

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ȱ ȱ ȱ ȱ

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Figure

Table 7.-1 Paracetamol data [348].
Figure 1. TOC decay vs electrolysis time for the degradation of 100 mL of�1 mM Fe1 mM Fe100 mA cmNone3-cm�157 mg L−1 paracetamol solutions in 0.05 M Na2SO4 of pH 3.0 at−2 and at 35°C, using a cell with a 3-cm2 Pt anode and a2 O2-diffusion cathode for H2O2
Table I. Effect of applied current on the percentage of TOC removal and MCE for the degradation of 157 mg L−13.0 at 35°C by indirect electro-oxidation methods with H paracetamol solutions of pH2O2 electrogeneration using different catalysts under selected experimental conditions.
Figure 5. TOC removal with electrolysis time for the treatment of 100-mL35°C:Cuand Cusolutions of pH 3.0 containing 157 mg L−1 paracetamol and different Fe2+2+ concentrations under UVA irradiation, at 100 mA cm−2 and at ��� 0.25 mM Fe2+ + 0.25 mM Cu2+, ��� 1 mM Fe2+ + 0.25 mM2+, ��� 0.25 mM Fe2+ + 1 mM Cu2+, and ��� 1 mM Fe2+ + 1 mM Cu2+.
+7

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