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Dinuclear dialkoxo bridged cyclopentadienylsiloxo titanium complexes

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Figure

Fig. 1 Compound A.
Fig. 2 ORTEP diagrams of [(TiCl) 2 (m-O 2 L)(m- {(h 5 -C 5 Me 4 SiMeO) 2 (m-O) })] (O 2 L = 1,2-O 2 C 2 H 4 1a, 1,2-O 2 C 6 H 4 1b)
Table 1 Selected bond distances (A ˚ ) and angles ( ◦ ) of compounds 1a ·0.5C 6 H 14 , 1b, 7, [(TiCl 2 ) 2 (m- {(h 5 -C 5 Me 4 SiMeO) 2 (m-O) })] (A), [(TiCl 2 ) 2 (m- {h 5 - -C 5 R 4 SiMe 2 O } 2 )] (R = H B, 32 Me C 39 ) and [(TiMe 2 ) 2 (m-CH 2 )(m-{h 5
Table 3 Crystal data and structure refinement details for 1a ·0.5C 6 H 14 , 1b and 7

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