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Thermodynamic properties and phase equilibria of branched chain fluids using first- and second-order Wertheim’s thermodynamic perturbation theory

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Figure

FIG. 2. Schematic representation of the formation of branched chains using Wertheim’s first- and second-order perturbation theory
Figure 4 共a兲 shows the compressibility factor, as a func- func-tion of the packing fracfunc-tion, of four different hard chains.
FIG. 4. Compressibility factor, as a function of the packing fraction, of linear and branched hard chains: 共a兲 in the whole fluid range; 共b兲  enlarge-ment of the low packing fraction region
FIG. 5. Compressibility factor, as a function of the packing fraction, of linear and branched hard chains with 共a兲 six, ten, and 共b兲 sixteen segments.
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