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Strategies to Fabricate Polypeptide Based Structures via Ring Opening Polymerization of N Carboxyanhydrides

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Figure 7. Structure and reactive centers in α-amino acid N-carboxyanhydrides.
Figure 12. Propagation Reactions of the Mechanism for the Polymerization of NCAs with bipyNi  (COD) (bipy) 2,2-bipyridyl, (COD 1,5-cyclooctadiene) or (PMe 3 ) 4 Co complexes proposed by Deming  et al
Figure 13. Tentative mechanism of the ring-opening polymerization of NCAs (ZLLys, R = (CH 2 ) 4 NHC(O)OCH 2 C 6 H 5 ) using primary amine–hydrochlorides (chloride ions omitted)
Figure 14. Hexamethyldisilazane  (HMDS)-mediated NCA polymerization through trimethylsilyl  (TMS) carbamate group
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