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Isomerization of Fatty Acids A Cellular Barrier Mechanism in Nanotechnology?

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Academic year: 2020

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Figure

Figure 1. Cis-trans isomerization of unsaturated fatty acids present in phospholipids of cellular membranes in the presence of thiyl radicals (RS  ) as a proposed mechanism of cell barrier against nanoparticles.
Figure 2. Radical intermediary formed in a terminal double bond dur- dur-ing thiol-eno coupldur-ing.
Figure 4. NMR of 13 C (100 MHz, CDCl 3  of 11-(2-hydroxyethyl)methyl undecenoate.
Figure 5 shows C C conversion through time; as can be seen, between F1 and the F2, where only the thiol  con-centration varies (an increase of 0.3 mol), the conversion increases remarkably during the reaction process
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