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Kinetic and thermodynamic studies on transmetalation reactions

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Figure 1. Profile of the exchange reaction M1 + M2 to give M3 + M4, showing the  experimental value for TS1 and TS2 in THF at  ︎ -10 ºC and the calculated values  (Ref
Table  I-1.  K eq   for  Sn/Au  transmetalation  (L 1   =  PPh 3 ;  L 2   =  AsPh 3 ;  L 3   =  PMe 3 )
Figure II-4. Calculated Gibbs energy profile (kcal.mol –1 , at 323 K and p = 301atm, see  SI  for  details)  in  THF  for  the  reaction  of  [AuPh(PMe 3 )]  with  SnBu 3 Cl  to  produce  [AuCl(PMe 3 )]  and  SnBu 3 Ph
Figure  II-6.  IR  spectrum  in  THF  solution  of  [Au(OTf)(PMe 3 )]  (blue  line)  and  [AuCl(PMe 3 )]  (green  line)
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