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Properties of nitrogen vacancy centers in diamond: the group theoretic approach

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Figure

Table 2. Matrix elements for orbital operators in the C 3 v point group. For the T d
Figure 1. Energy diagram of the unperturbed NV center in diamond. Note that each electronic configuration can contain triplets (left column) as well as singlets (right column), which have been drawn in separate columns for clarity.
Figure 2. Splitting due to spin–orbit and spin–spin interactions in triplet ae.
Table 3. Selection rules for optical transitions between the triplet excited state (ae) and the triplet ground state (e 2 ), the singlets (ae) and the singlets (e 2 ), and the singlet (a 2 ) and the singlets (ae)
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