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Studies on a supersonic thermal plasma expansion process for synthesis of titanium nitride nanoparticles

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Academic year: 2020

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Fig. 2. XRD patterns of the as synthesized titanium nitride particles (13.2 kW, 30 mbar sample collection chamber pressure) by injecting the reactants at the colder tail zone for (a) NH 3 /TiCl 4 molar ratio of 14 and (b) molar ratio of 21, showing presenc
Fig. 5. TEM photograph of the TiN nanoparticles synthesized at lower sample collection chamber pressure of 10 mbar (13.2 kW and NH 3 /TiCl 4 molar ratio of 14) for (a) hot zone configuration and (b) colder tail zone configuration.
Fig. 6. HRTEM photograph of the TiN nanoparticles synthesized at lower sample collection chamber pressure of 10 mbar (13.2 kW and NH 3 /TiCl 4 molar ratio of 14) for colder tail zone configuration (a) unmarked and (b) marked, which show clear cubic shape pa
Fig. 7 shows HRTEM photographs of the particles synthesized by injecting reactants to the two different zones under reduced pressure.
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