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Amidinate Aluminium Complexes as Catalysts for Carbon Dioxide Fixation into Cyclic Carbonates

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Table 1. Conversion of styrene oxide 7a into styrene carbonate 8a by using catalysts 1–6 and Bu 4 NBr
Table 3. Conversion of styrene oxide 7a into styrene carbonate 8a by using catalysts 1–6 and TBAI
Table 5. Synthesis of disubstituted cyclic carbonates by using complex 2 as catalyst. [a]
Figure 4. Logarithmic plots of k 0 obs and k 1 obs vs. [2]. Reactions were carried out at 508C under solvent-free conditions with [2]=87–612 mm and [TBAI] =440 mm

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