2. ESTUDIO DE MEZCLAS LIPOFILICAS EN RESONANCIA MAGNÉTICA
2.3. Quimiometría basada en RMN
2.3.4. Análisis Estadístico Multivariable
Plant Discharge Crusher Hot Screen Cooler Cold Screen
Bethlehem, IN Baghouse Baghouse Baghouse None N/A
Inland Steel, IN Baghouse Baghouse Baghouse Baghouse None
LTV Steel, IN Scrubber Scrubber Scrubber None None
U.S. Steel, IN Baghouse Baghouse Baghouse None Baghouse
Bethlehem, MD Baghouse Baghouse Baghouse Cyclone Baghouse
AK Steel, OH Baghouse Baghouse Baghouse Baghouse Water sprays
WCI Steel, OH Baghouse Baghouse Baghouse Baghouse Baghouse
Wheeling-Pitt, OH Baghouse N/A N/A Water sprays Water sprays
Geneva Steel, UT Rotoclone N/A Rotoclone N/A N/A
* Certain transfer points are controlled by the discharge baghouse. 4.1.3 Materials Handling
Emissions from material handling are generally fugitive emissions and are usually uncontrolled.
These emissions result from material storage, materials mixing, and sinter storage. Fugitive emissions
escaping the raw material handling equipment are normally confined within the building in which they are
processed, and primarily affect the worker environment. Only one sinter plant in the country uses a
baghouse to control emissions from material storage and handling; the remaining plants use no control.
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the building. One plant, however, uses water sprays to wet the materials at the various transfer points.
While water sprays by themselves may be effective on materials such as dry ore, they are not effective
in controlling hot fines. Emissions from sinter storage are generally uncontrolled, although one plant
uses chemical dust suppression on the product.
4.1.4 Capture and Control System Performance.
Windbox capture efficiencies were reported by six companies in a 1993 industry survey and by
one company in a 1991 screening survey response. These efficiencies range from 93 to 99.9 percent
based on engineering estimates. Control device efficiencies varied considerably, ranging from 96.2 to
99.5 percent for a baghouse and from 70 to 99+ percent for a wet scrubber.
4.1.5 Pollution Prevention
Pollution from sinter plants is generated by particulate emissions from various emission points
and by organic emissions from the windbox. Sinter plants serve as a means of recycling waste iron-
bearing materials that would otherwise be landfilled from other processes at an integrated iron and steel
facility and within the sinter plant itself. The use of sinter plants is an effective pollution prevention
measure, but significant quantities of particulate and organic compounds are generated as a result of the
recycling process.
One of the major sources of organic emissions in the sinter plant is from oily mill scale blended
into the feed materials. One way to reduce organic emissions in the sinter plant would be to set a limit
for the oil content of the sinter mixture or for the amount of oily mill scale that a plant may use. Even
though a high energy wet scrubber may be able to handle larger quantities of oil than a comparable
baghouse system, limiting the amount of oil for all plants may reduce organic emissions. Another option
4.2 BLAST FURNACE 4.2.1 Casthouse
Emissions from molten iron and slag occur primarily at the tap hole of the blast furnace and in
the iron trough immediately adjacent to it. Emissions also result from the runners that transport the iron
and slag and from the ladle that receives the molten iron. These emissions include flakes of graphite
(carbon) called "kish" that is released as the metal cools (because the solubility of carbon in the metal
decreases as it cools) and metal oxides that form when the reduced metal (e.g., iron, manganese) reacts
with oxygen in the air.19 Factors affecting these emissions include the duration of tapping, exposed
surface area of metal and slag, length of runners, and the presence/absence of runner covers and flame
suppression, which reduce contact with air.
Table 4-3 presents the capture and control systems in place on each furnace in the industry.
Three furnaces at three facilities did not report the presence of capture or control systems for emissions
from the casthouse. A combination of flame suppression and covered runners is most commonly used
at the remaining furnaces in the industry; in addition, more than one-third of the furnaces evacuate
emissions to a control device, most commonly a baghouse.
Flame suppression consists of blowing natural gas over the iron runners and torpedo cars. The
combustion of the gas consumes oxygen, which suppresses emissions. In addition to flame suppression,
many facilities use covered runners on the iron and slag runners. Most furnaces have a removable
cover over the iron trough; the cover is removed during drilling of the furnace and is quickly put back
into place when the molten iron starts to flow. The cover is removed again at the end of the tap to plug
the taphole with refractory clay.
One method of controlling emissions from the casthouse is to totally enclose the casthouse and
evacuate it to a baghouse. Alternatively, there may be localized hooding over the iron trough, iron and
slag runners, and hot metal ladles that are evacuated to a baghouse. Two furnaces at one facility use a
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