• No se han encontrado resultados

DISCUSIÓN

In document FACULTAD DE DERECHO Y HUMANIDADES (página 35-58)

Sodium carbonate sol.100 kg

Aqueous layer 120 kg

Sent to ETP

Packing

Neutralization

Sr.No Chemical Name CAS No. Type of Hazard Toxicological information LD50 (LC50) Flash Point BP Sp Gravity

LEL UEL Solubility With Water

Incompeteble Material Hazardous Combustion Products

Health Fire Reacti vity

ERPG,ppm ppm degC degC % % H F R

1 Butyl Methacrylate 97-88-1 Flammable /Toxic Yes yes yes 16000 52.2 160 0.894 2 8 insoluble in coldand hot water

reactive with oxidicing agent and reducing agent ,acids ,alkali. And

with moisture.

2 2 0 Carbon MonoxideCarbon Dioxide

2 Butyl Acetate 123-86-4 Flammable Yes yes No 10768 23.9 126.5 0.9 1.7 7.6 Partially solublein cold water Not Available 1 3 0 Carbon MonoxideCarbon Dioxide

3 Ethyl Acetate 140-78-6 Flammable Yes yes No (LC505620

45000)

open cup 7.2 close

cup -4.4 77 0.902 2.2 9

Soluble in cold and hot water

Reactiv with oxidising

agents, acid and alkali 2 3 0

Carbon Dioxide Carbon Monoxide

4 Formaldehyde 37% 50-00-0 Flammable Yes yes No 100 open cup 60 close

cup 50 98 1.08 6 36.5

Easily Soluble in hot and cold

water

reactive with oxidicing agent and reducing agent ,acids ,alkali.

3 2 0 Carbon Dioxide Carbon Monoxide

5 Phenol 108-95-2 Flammable Yes yes No 270 open cup 85 close

cup 79 182 1.057 1.7 8.6

Soluble in cold water

reactive with oxidicing agent, metals, acids

,alkali.

4 2 0 Carbon Dioxide Carbon Monoxide

6 Sulphuric Acid 7664-93-9 FlammableNon Yes No yes 2140 Not Applicable 270 1.84 NA NA Easily Soluble incold water

reactive with oxidicing agent, Reducing agents, Cumbustible

material, Organic material, metals, acids

,alkali, moisture.

3 0 2 Not Available

7 Styrene 100-42-5 Flammable Yes yes yes 2650 open cup 36.7close cup 31.1 145.2 0.906 1.1 6.1

Very slightly Soluble in cold

water

Not Available 2 3 2 Carbon MonoxideCarbon Dioxide

8 Xylene 1330-20-7 Flammable Yes yes No 4300 open cup 37.8

close cup 24 138.5 0.864 1 7

insoluble in cold and hot water

Reactive with oxidicing

agent, acids . 2 3 0

Carbon Dioxide Carbon Monoxide

9 Acetic Acid 64-19-7 Flammable Yes yes No 3310 open cup 43 closecup 39 118.1 1.049 4 19.9

Easily Soluble in Hot and cold

water

Reactive with oxidicing agent, metals, acids

,alkali.

3 2 0 Carbon MonoxideCarbon Dioxide

10 Ethylne Diamine 107-15-3 Flammable Yes yes No 500 34 117.2 0.9 4.2 Easily Soluble in

cold water Not Available 3 3 0

Carbon Dioxide and nitrogen oxides

NO,NO2 Carbon Monoxide

11 Cyclohexanone 108-94-1 Flammable Yes yes No 1516 open cup 46 close

cup 43.889 155.6 0.948 1.1 9.4

Partially Soluble in Hot and cold

water

Reactive with oxidicing

agent, acids ,alkali. 1 2 0

Carbon Dioxide Carbon Monoxide

12 Toluene 108-88-3 Flammable Yes yes No 636 open cup 16 close

cup 4.4444 110.6 0.864 1.1 7.1

Practically insoluble in

water

Reactive with oxidicing

agent. 2 3 0

Carbon Dioxide Carbon Monoxide

13 Hydrogen Gas 1333-74-0 Extreamly

Flammable No yes No

Not Available

No Information

Available -252.8 4 75 soluble in water

Reactive with oxidicing

agent. 0 4 0 Not Available

14 Acrylonitrile 1017-13-1 Flammable /Toxic Yes Yes No STEL 10 333 0 77 0.806 3.1 17

Very slightly soluble in cold

water, hot water

incompatible with oxidizing agents, such as metals, acids, alkalis

3 3 1 Carbon MonoxideCarbon Dioxide

15 Methyl Ethyl

Ketone(MEK) 78-93-3

Flammable/To

xic Yes Yes No STEL:300ppm 6480 -9 79.6 0.805 1.8 10

Soluble in cold water

Reactive with oxidizing agents, metals, acids,

alkalis.

1 3 0 Carbon Oxides

( CO2,CO)

16 IPA (Isopropyl

Alcohol) 67-63-0 Flammable Yes Yes No NA NA 11.67 82.5 0.785 2 12.7

Easily soluble in cold water, hot

water,

Reactive with oxidizing

agents, acids, alkalis. 1 3 0

Carbon Oxides ( CO2,CO)

17 Ethyl Acrylate 140-88-5 Flammable/Toxic Yes yes yes TWA 25ppm (1414) 9 99.4 0.923 1.4 13 Partially solublein cold water

The product may undergo hazardous

decomposition, condensation or polymerization, it may

react violently with water to emit

toxic gases

2 3 2 Carbon Oxides( CO2,CO)

18 Methyl

Methacrylate 80-62-6

Flammable/To

xic Yes yes yes TWA 100 ppm

7872mg/

kg 19 100 0.936 2.1 12.5

Partially soluble in cold water

Reactive with metals,

acids, alkalis 2 3 3

Carbon Oxides ( CO2,CO)

19 Butanol 71-36-3 Flammable Yes yes no NA NA 36.1 117.7 0.81 1.4 11.2

Easily soluble in methanol, diethyl ether. Partially soluble in cold water, hot water, n- octanol

Highly reactive with oxidizing agents, reducing agents. Slightly reactive to reactive with organic materials, acids, alkalis

1 3 0 Carbon Oxides( CO2,CO)

20 MIBK 108-10-1 Flammble No yes No NA NA 14 115.9 0.8 1.4 7.5 Imiscible Avoid oxidizing &

reducing agents 1 3 0

Carbon Oxides ( CO2,CO)

Rapid EIA for Proposed Synthetic Organic Chemicals Manufacturing unit

at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch Details of Hazardous Chemicals Inventory, hazardous properties Polyols Polymers

Full name of the raw material

B.P.°C, M.P.°C Fl. P.°C LD50 mg/Kg or LC50 mg/l

Vapour pressure

Source As per Haz. Chemicals rules,2000 Consumption MT/Month No. of days No. MT Pressure kg/cm2 Temp °C

1 Acetic acid L 87.6 3 Al or SS Tank - AGT 1 10 Atm. 30-40°C BP 118.1°C MP 16.6°C 39 LD50- 3310 mg/kg LC50- 5620 mg/l-1h

1.5 kPa@ 20°C

indigenous Sch-1,part-I(b)-HF & Part-II

2 Acrylic Acid L 14.4 0 Drum 1 0.2 Atm. 30-40°C BP 141 °C MP 14°C 50 LD50-33500 mg/kg LC50-

5300 mg/l- 2h

0.5 kPa@ 20°C

indigenous Sch-1,part-I(a)-Toxic & Part-II

3 Acryl amide S 73.5 5 1 MT Jumbo bag 15 15 Atm. 30-40°C BP 125 °C MP 84.5°C 138 LD50- 124 mg/kg NA indigenous Sch-1,part-I(a)-Toxic & Part-II 4 acrylonitrile L 73.5 8 CS Tank - AGT 1 20 20 Atm. 30-40°C BP 77.3°C MP -82°C -1.11 LD50- 78 mg/kg LC50-

333 mg/l-4h

11.1 kPa@ 20°C

indigenous Sch-1,part-I(b)-VHF 5 Benzoyl peroxide S 2.76 5 50 kg bag 10 0.5 Atm. 30-40°C BP 103°C MP-104.5°C NA LD50- 7710 mg/kg NA indigenous Sc-I, part-II 6 Bisphenol-A S 207 3 1 MT Jumbo bag 20 20 Atm. 30-40°C BP 220°C MP 158-159°C 227 LD50- 2000-5000 mg/kg

LC50- 170 mg/l-6h

NA indigenous Sc-I, part-II

7 Butanol L 3.15 95 CS or SS Tank -

AGT

1 10 Atm. 30-40°C BP 117.7°C MP -89.5 28.9 LD50- 790 mg/kg 0.6 kPa@ 20°C

indigenous Sch-1,part-I(b)-HF

8 Butyl acetate L 3.15 95 CS or SS Tank - AGT

1 10 Atm. 30-40°C BP 126.5, MP -77.9 23.9 LD50- 10768 mg/kg 1.3 kPa@ 20°C

indigenous Sch-1,part-I(b)-HF

9 butyl acrylate L 73.5 8 Drum 100 20 Atm. 30-40°C BP 145°C MP -64.6°C 29 LD50- 900 mg/kg

LC50- 2730 mg/l-4h

0.5 kPa@ 20°C

indigenous Sch-1,part-I(b)-HF 10 Butyl methacrylate L 27.6 22 Drum 100 20 Atm. 30-40°C BP 160°C MP -75°C 52.2 LD50-16000 mg/kg 0.7 kPa@

20°C

indigenous Sch-1,part-I(b)-HF

10 Caustic soda flakes S 22 68 Jambo Bag 50 50 Atm. 30-40°C BP 1388°C MP 323°C NA NA NA indigenous Sc-I, part-II

11 Cyclohexanone L 240 5 CS or SS Tank - AGT

2 40 Atm. 30-40°C BP 155.6°C MP -31°C 43.89 LD50- 1516 mg/kg 0.7 kPa @ 26.7°C

imported / indigenous Sch-1,part-I(b)-HF

12 Di butyl tinoxide S 1.5 4 Drum 1 0.2 Atm. 30-40°C MP >300°C NA oral-LD50-44.9 mg/kg NA indigenous Sch-1,part-I(a)-highly Toxic 13 Ethyl acetate L 3.15 19 Drum 10 2 Atm. 30-40°C BP 77°C, MP -83°C -4.4 LD50- 5620 mg/kg, LC50-

16000 mg/l -6h

12.4 kPa@ 20°C

indigenous Sch-1,part-I(b)-VHF, Sc-I, part-II

14 ethyl acrylate L 73.5 8 CS or SS Tank - AGT 2 20 Atm. 30-40°C BP 99.4°C MP -72°C -2 LD50- 800 mg/kg LC50- 1414 mg/l-4h 29 mm Hg @ 20°C indigenous Sch-1,part-I(b)-VHF

15 Ethyl methacrylate L 73.5 8 Drum 100 20 Atm. 30-40°C BP 118-119°C MP -60°C 19 LD50- 13424 mg/kg LC50- 8300 ppm-4h

20hPa @ 20°C

indigenous Sc-I,part-I(b)-VHFpart-II

16 Ethylene Diamine L 93 3 Drum 50 10 Atm. 30-40°C BP 117.2°C MP 8.5°C 34 LD50- 500 mg/kg, LC50- 424.3 mg/l-4h

10.7 mm Hg @ 20°C

indigenous Sch-1,part-I(b)-HF, Sc-I, part-II

17 ethylene glycol L 207 3 Drum 100 20 Atm. 30-40°C BP 197.6°C MP -13°C 111 LD50- 4700 mg/kg

LC50- 200 mg/m-4h

6 mm Hg @ 20°C

indigenous Sc-I, part-II

18 Formaldehyde (37%) L 1083 3 CS or SS Tank - AGT

2 100 Atm. 30-40°C BP 98°C MP -15°C 50 LD50-100 mg/kg, LC50- 64000 mg/l -4h

2.4 @ 20°C indigenous Sch-1,part-I(b)-HF, Sc-I, part-II

19 Hydrogen gas G 14.7 10 Cylinder 30 5 2 150-200 30-40°C BP -252.8°C MP -259°C NA NA NA indigenous Sc-I, part-II

20 Iso Propyl Alcohol L 3.15 190 CS or SS Tank - AGT

1 20 Atm. 30-40°C BP 82.5°C MP -88.5°C 11.7 LD50- 5045 mg/kg 4.4 kPa@ 20°C

indigenous Sc-I, part-II

21 methacrylic acid L 73.5 8 Drum 100 20 Atm. 30-40°C BP 163°C MP 16°C 77 LD50- 1250 mg/kg 0.975 mm

Hg @ 20°C

indigenous Sch-1,part-I(b)-F

22 methyl acrylate L 73.5 8 Drum 100 20 Atm. 30-40°C BP 80.5°C MP -76.5°C -3.89 LD50- 277 mg/kg NA indigenous Sch-1,part-I(b)-VHF 23 methyl cyclohexanone L 240 3 Drum 100 20 Atm. 30-40°C BP 162-163°C MP -13.9°C 48 LD50- 1980 mg/kg 1hPa @

20°C

imported / indigenous Sch-1,part-I(b)-HF

24 Methyl Ethyl Ketone L 240 1 CS Tank - AGT 1 10 Atm. 30-40°C BP 79.6°C, MP -86°C -9 LD50-2737 mg/kg, LC50- 23500 mg/m -8h

10.3 kPa@ 20°C

imported / indigenous Sch-1,part-I(b)-VHF

25 methyl isobutyl ketone L 240 3 CS Tank - AGT 1 20 Atm. 30-40°C BP 115.9°C MP -84°C 14 LD50- 1600 mg/kg LC50- 8000 mg/l-4h

15.7 mm Hg @ 20°C

imported / indigenous Sch-1,part-I(b)-VHF

26 Methyl methacrylate L 79.2 8 CS or SS Tank - AGT

1 20 Atm. 30-40°C BP 100°C MP -48°C 13 LD50-7872 mg/Kg LC50- 5303.3 mg/l-4h

29 mm Hg @ 20°C

indigenous Sch-1,part-I(b)-VHF, Sc-I, part-II

27 Paraformaldehyde S 1083 1 Jambo Bag 50 50 Atm. 30-40°C MP 120-170 °C 70 LD50-800 mg/kg, LC50- 1070 mg/m-4h

NA imported / indigenous Sch-1,part-I(b)-F

28 Phenol L 727.5 2 CS Tank - AGT 1 40 Atm. 30-40°C BP 182°C, MP 42°C 79 LD 50-dermal- 630 mg/kg NA imported Sch-1,part-I(a)- Toxic, Sch-1,part-I(b)-F, Sc-I, part-II

29 Poly Vinyl Alcohol S 0.02 750 50 kg bag 10 0.5 Atm. 30-40°C MP 200°C 79 LD50->20000 mg/kg NA indigenous Sch-1,part-I(b)-F

30 propylene glycol L 207 3 Drum 100 20 Atm. 30-40°C BP 188°C MP -59°C 99 LD50- 20000mg/kg 0 kPa@

20°C

indigenous Sc-I, part-II

31 Styrene L 336 4 CS Tank - AGT 2 40 cool 15-21°C BP 145.2°C MP -30.6°C 31.1 LD50-2650 mg/kg, LC50-12000 mg/l-4h

4.5 mm Hg @ 20°C

imported/ indigenous Sch-1,part-I(b)-HF, Sc-I, part-II

32 Sulphuric acid L 35.1 9 CS Tank - AGT 1 10 Atm. 30-40°C BP 270-340°C, MP -35°C NA LD50- 2140 mg/kg, LC50-510mg/m -2h

NA indigenous Corrosive,Sc-I, part-II

33 Toluene L 91.5 13 CS Tank -UGT 2 40 Atm. 30-40°C BP 110.6°C, MP -95°C 4.44 LD50-636 mg/kg, LC50- 49000 mg/m-4h

3.8 kPa @ 25°C

indigenous Sch-1,part-I(b)-VHF, Sc-I, part-II

34 Xylene L 199.5 3 CS Tank -UGT 1 20 Atm. 30-40°C BP 138.5°C MP -47.4°C 24 LD50- 4300 mg/kg 0.9 kPa@ 20°C

indigenous Sch-1,part-I(b)-HF, Sc-I, part-II

35 Terpentine-Product L 67 9 CS Tank -AGT 1 20 Atm. 30-40°C BP 165°C 35 LD50- 5760 mg/kg - - -

Sr. No. State i.e,

solid / Liquid /

Gas

Inventory Equipment consider No. of container & Size at site

Storage Parameters

AGT - Aboveground Tank UGT - Underground tank HF - Highly flammable VHF - Very Highly flammable

MAH threshold

In document FACULTAD DE DERECHO Y HUMANIDADES (página 35-58)

Documento similar