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Norma del Reglamento del ACI 318S-08 Establecida Para el Diseño de Sistemas de Anclaje al Concreto: Apéndice D

DEFINICIÓN DEL TEMA DE INVESTIGACIÓN Y JUSTIFICACIÓN DEL MISMO

2.5 Norma del Reglamento del ACI 318S-08 Establecida Para el Diseño de Sistemas de Anclaje al Concreto: Apéndice D

Following 8 and 16 weeks of supplementation with Se supplemented with vitamin C and vitamin E (AS7), decrease in levels of LPO and 8-OHdG were found in supplemented Groups two and three (Group two+AS and Group three+AS) when compared with non-supplemented Groups two and three (Group two–AS and Group three–AS). Increases in TAS, vitamin C, vitamin E and Se levels, GPx activities were observed in Group two+AS and Group three+AS compared with Group two–AS and Group three–AS (Figures 4.1a–4.8b).

The ABDEFS wound healing assessing tools revealed reduction in score of supplemented diabetic foot ulcer and increase in score of non-supplemented diabetic foot ulcer subjects (Figure 4.9).

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Table 4.9. Selenium, Vitamins C and E (S7) supplementation on oxidative stress indices and antioxidant status in supplemented and non-supplemented rats

Paramete rs/Groups

Group A Group B Group C Group D Group E

Before Supple mentati on

After Supple mentati on

*%

differ ences

Before Supple mentati on

After Supple mentati on

*%

differ ences

Before Supple mentati on

After Supple mentati on

*%

differ ences

Before Supple mentati on

After Supple mentati on

*%

differ ences

Before Supple mentati on

After Supple mentati on

*%

differ ences 4–HNE

(μg/ml) 11.979

± 0.763

11.630

± 0.467

–2.91 12.114

± 0.666

11.521

± 1.080

–4.90 12.789

± 0.763

11.665

± 0.274

–8.79 12.241

± 0.045

10.956

± 0.117 10.50

13.517

± 0.124

10.772

± 0.133 20.31 LPO

(μmol/l)

102.761

± 2.062

95.063

± 1.302

–7.49 123.984

± 10.879

110.085

± 3.820 11.21

162.721

± 30.753

155.065

± 14.591

–4.70 138.161

± 3.075

108.203

± 6.238 21.68

186.541

± 1.831

142.810

± 23.663

23.44 8–OHdG

(ng/ml)

3.559 ± 0.310

3.095 ± 0.618

13.04

5.139 ± 0.495

4.041 ± 0.018

21.37

5.612 ± 0.159

4.782 ± 0.090

14.79

5.541 ± 0.619

3.956 ± 0.032

28.60

6.697 ± 0.029

4.516 ± 0.103

32.57 SOD

(U/g Hb)

5058.42 4 ± 289.245

5498.72 7 ± 46.130

8.70 4294.20 4 ± 447.366

4680.32 9 ± 86.175

8.99 4555.47 2 ± 26.055

5031.92 2 ± 28.509

10.46 4105.10 6 ± 70.416

4922.42 3 ± 180.827

19.91 4432.79 5 ± 95.389

5211.57 4 ± 590.057

17.57

GPx (U/g Hb)

1068.98 1 ± 7.887

1080.73 2 ± 42.510

1.10 1137.62 1 ± 38.723

1176.58 9 ± 70.291

3.43 1099.56 2 ± 9.899

1140.26 5 ± 151.378

3.70 1184.10 6 ± 114.002

1177.00 0 ± 18.859

–0.60 1109.00 5 ± 62.543

1141.36 5 ± 28.878

2.92

TAS (mmol/l)

0.726 ± 0.095

0.742 ± 0.168

2.20 0.667 ± 0.325

0.707 ± 0.129

6.00 0.550 ± 0.028

0.584 ± 0.058

6.18 0.620 ± 0.063

0.707 ± 0.127

14.03 0.516 ± 0.045

0.585 ± 0.153

13.37 Vitamin

C (mg/dl)

0.069 ± 0.010

0.078 ± 0.014

13.04 0.071 ± 0.022

0.088 ± 0.008

23.94 0.067 ± 0.011

0.084 ± 0.009

25.37 0.065 ± 0.003

0.067 ± 0.007

3.08 0.061 ± 0.011

0.075 ± 0.014

22.95 Vitamin

E (mg/dl)

0.789 ± 0.094

0.932 ± 0.088

18.12 0.555 ± 0.020

0.665 ± 0.093

19.82 0.537 ± 0.081

0.741 ± 0.147

37.99 0.527 ± 0.026

0.715 ± 0.181

35.67 0.518 ± 0.007

0.835 ± 0.060

61.20 Se

(μmol/l)

0.230 ± 0.074

0.236 ± 0.010

2.61 0.227 ± 0.034

0.231 ± 0.014

1.76 0.199 ± 0.023

0.221 ± 0.016

11.06 0.224 ± 0.012

0.230 ± 0.013

2.68 0.194 ± 0.005

0.219 ± 0.010

12.89 Results are expressed as Mean ± S.D

*supplemented Groups A, B, C, D and E were compared with non-supplemented Groups A, B, C, D and E

% = Percentage increases and decreases where negative (–) values denotes percentage decreases and positive (+) values percentage increases Group A = non-diabetic Control rats without ulcer

Group B = Diabetic Rats without Ulcer Group C = Diabetic Rats with Ulcer

Group D = Glibenclamide treated Diabetic Rats without Ulcer Group E = Glibenclamide treated Diabetic Rats with Ulcer

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Table 4.10. The Friedman significant table of rats results of supplemented Groups A, B, C, D and E compared with supplemented groups in all the supplementations (S1 to S7)

Groups 4-HNE

(µg/ml)

LPO (µmol/l) 8-OHdG

(ng/ml)

SOD (U/g Hb) GPx (U/g Hb) TAS (mmol/l) Vitamin C (mg/dl)

Vitamin E (mg/dl)

Se (µmol/l)

Fried-man

P-value

Fried-man

P-value

Fried-man

P-value

Fried-man

P-value

Fried-man

P-value

Fried-man

P-value

Fried-man

P-value

Fried-man

P-value

Fried-man

P-value

†Before Supplementation

A, B, & C 1.733NS 0.420 8.000* 0.018 6.000 0.050 6.500* 0.039 8.000* 0.018 6.500* 0.039 0.500NS 0.779 6.500* 0.039 1.500NS 0.472 A, D & E 6.500* 0.039 8.000* 0.018 8.000* 0.018 8.000* 0.018 3.500NS 0.174 4.500NS 0.105 0.933NS 0.627 6.000 0.050 4.500NS 0.105

#After Supplementation

A1, B1 & C1 2.000NS 0.368 8.000* 0.018 8.000* 0.018 6.500* 0.039 0.500NS 0.779 6.000 0.050 0.000NS 1.000 8.000* 0.018 2.000NS 0.368 A1, D1 & E1 6.000 0.050 8.000* 0.018 6.000 0.050 3.500NS 0.174 0.500NS 0.779 2.800NS 0.247 2.000NS 0.368 3.500NS 0.174 2.000NS 0.368 A2, B2 & C2 8.000* 0.018 8.000* 0.018 8.000* 0.018 3.500NS 0.174 4.500NS 0.105 8.000* 0.018 2.000NS 0.368 8.000* 0.018 1.733NS 0.420 A2, D2 & E2 8.000* 0.018 8.000* 0.018 8.000* 0.018 6.500* 0.039 6.500* 0.039 8.000* 0.018 0.500NS 0.779 4.500NS 0.105 0.500NS 0.779 A3, B3 & C3 2.000NS 0.368 8.000* 0.018 6.500* 0.039 8.000* 0.018 2.800NS 0.247 8.000* 0.018 3.500NS 0.174 6.000 0.050 0.400NS 0.819 A3, D3 & E3 1.500NS 0.472 8.000* 0.018 6.500* 0.039 4.500NS 0.105 6.000 0.050 3.500NS 0.174 8.000* 0.018 6.500* 0.039 3.500NS 0.174 A4, B4 & C4 1.500NS 0.472 8.000* 0.018 8.000* 0.018 6.500* 0.039 6.500* 0.039 8.000* 0.018 0.500NS 0.779 8.000* 0.018 0.933NS 0.627 A4, D4 & E4 3.500NS 0.174 8.000* 0.018 6.500* 0.039 2.000NS 0.368 6.500* 0.039 6.500* 0.039 3.500NS 0.174 8.000* 0.018 0.500NS 0.779 A5, B5 & C5 6.500* 0.039 6.500* 0.039 8.000* 0.018 8.000* 0.018 8.000* 0.018 2.000NS 0.368 1.200NS 0.549 0.500NS 0.779 3.500NS 0.174 A5, D5 & E5 8.000* 0.018 4.500NS 0.105 8.000* 0.018 8.000* 0.018 3.500NS 0.174 1.500NS 0.472 0.500NS 0.779 0.500NS 0.779 0.000NS 1.000 A6, B6 & C6 6.500* 0.039 0.500NS 0.779 6.000 0.050 8.000* 0.018 4.500NS 0.105 4.500NS 0.105 1.500NS 0.472 1.500NS 0.472 0.400NS 0.819 A6, D6 & E6 6.500* 0.039 8.000* 0.018 6.500* 0.039 3.500NS 0.174 4.500NS 0.105 6.000 0.050 1.500NS 0.472 6.000 0.050 0.933NS 0.627 A7, B7 & C7 0.000NS 1.000 8.000* 0.018 8.000* 0.018 8.000* 0.018 2.000NS 0.368 3.500NS 0.174 2.286NS 0.319 6.500* 0.039 2.364NS 0.307 A7, D7 & E7 3.500NS 0.174 8.000* 0.018 8.000* 0.018 2.000NS 0.368 6.500* 0.039 2.000NS 0.368 2.286NS 0.319 6.000 0.050 3.000NS 0.223

†Non-supplemented Groups B and C and Groups D and E were compared with non-supplemented Group A at the beginning of the study.

#Supplemented Groups B and C and Groups D and E were compared with Supplemented Group A.

Not significant = NSP > 0.05 *Significant at p < 0.05

Group A = non-diabetic control rats without ulcer Group B = Diabetic rats without ulcer Group C = Diabetic Rats with Ulcer Group D = Glibenclamide treated diabetic rats without ulcer Group E = Glibenclamide treated diabetic rats with ulcer

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A. Rat Tissue with Fibroblast B. Rat Tissue with Fibroblast 2

C. Rat Tissue with Fibroblast 3 D. Rat Tissue with Fibroblast 4

E. Normal Tissue of Rat F. Normal Tissue of Rat

Figure 4.03a. Healing process in Wistar rats as depicted by the presence of fibroblast and granulated Tissues (A – F)

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G. Rat Tissue with granulation cells 1 H. Rat Tissue with granulation cells 2

I. Rat Tissue with granulation cells 3 J. Rat Tissue with granulation cells 4

K. Normal Tissue of Rat L. Normal Tissue of Rat

Figure 4.03b. Healing process in Wistar rats as depicted by the presence of fibroblast and granulated Tissues (G – L)

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Table 4.11. The comparison of parameters at 8 and 16 weeks of antioxidant supplementation with baseline parameters in Group two and Group three using percentage differences

Before Antioxidant Supplementation

8 and 16 weeks Antioxidant

Supplementation in DM with and without DFU

8 and 16 weeks of non – Antioxidant Supplementation in DM with and without

DFU Parameters *Group

two (%) 0 week

n = 56

*Group three (%)

0 week n = 70

¶Group two (%) 8 week

†n = 25

¶Group2 (%) 16week

†n =25

¶Group three (%)

8 week

†n = 25

¶Group three (%)

16week

†n = 25

¶Group2 (%) 8 week

†n = 25

¶Group2 (%) 16 week

†n = 25

¶Group three

(%) 8 week

†n = 25

¶Group three

(%) 16 week

†n = 25

BMI(Kg/m2) +20.80 +13.74 –5.27 –8.18 –4.55 –6.58 –3.51 –6.73 –3.84 –6.07

FPG (mg/dl) +138.90 +155.13 –5.78 –7.70 –4.79 –9.61 –5.90 –12.94 –4.71 –10.34

HbA1c (%) +89.22 +111.76 –13.53 –18.79 –5.13 –9.44 –10.10 –11.76 –5.75 –8.06

LPO (µmol/l) +42.60 +76.60 –7.43 –10.54 –12.55 –22.53 +4.20 +7.63 +12.44 +23.10

8-OHdG(ng/ml) +46.72 +56.76 –6.71 –10.19 –10.49 –22.54 +14.34 +17.28 +12.46 +26.81

SOD (U/g Hb) –13.99 –3.27 +2.53 +3.56 –3.03 –0.43 –3.61 –5.66 –6.14 –11.29

GPx (U/g Hb) +68.66 +160.28 +5.30 +6.02 –4.77 +17.79 –1.60 –3.27 +5.66 +2.87

TAS (mmol/l) –53.52 –52.82 +7.81 +12.50 +4.55 +9.09 –4.41 –8.82 –7.25 –11.59

VitaminC(mg/dl) –20.00 –30.00 +44.93 +60.87 +6.00 +20.00 –8.57 –15.71 –13.24 –14.71 VitaminE(mg/dl) –20.00 –22.73 +19.76 +26.67 +22.03 +31.53 +5.41 +8.47 –4.69 –15.43

Se (µmol/l) –39.51 –40.74 +11.11 +18.67 +11.02 +19.54 –6.95 –13.68 –12.14 –16.96

ABDEFS – – – – –13.21 –24.81 – – +5.96 +14.04

*The percentage increases and decreases of Groups two and three were computed using Group one as reference at baseline.

†n = Number of subjects that completed the study

¶The percentage increases and decreases of supplemented and non-supplemented Groups two and three at 8 and 16 weeks were compared with Groups two and three at baseline respectively.

n = Number of subjects

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Figure 4.1a. Selenium, vitamin C and vitamin E supplementation effects on lipid peroxide (LPO) levels at baseline, 8 and 16 weeks in DM subjects without diabetic foot ulcer (Group two)

Group two + AS = Diabetes mellitus subjects without diabetic foot ulcer subjects administered with antioxidant supplementation

Group two – AS = Diabetes mellitus subjects without diabetic foot ulcer subjects not administered with antioxidant supplementation

At baseline, a non-significant change was observed when the LPO values of supplemented Group two was compared with the value of non-supplemented group. The supplementation at 8 and 16 weeks resulted in non-significant decreases of LPO levels in supplemented group compared with non-supplemented group.

44.40

41.10 39.72

45.19 ns

47.09 ns

48.64 ns

0 30 60

baseline 8 weeks 16 weeks

Values of LPO (µmol/L)

Group two + AS Group two – AS

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Figure 4.1b. Selenium, vitamins C and E supplementation effects on lipid peroxide (LPO) levels at baseline, 8 and 16 weeks in DM subjects with diabetic foot ulcer (Group three)

Group three + AS = Diabetes mellitus subjects with diabetic foot ulcer subjects administered with antioxidant supplementation

Group three – AS = Diabetes mellitus subjects with diabetic foot ulcer not administered with antioxidant supplementation

In this group, when LPO of supplemented group was compared with non-supplemented group at baseline, a non-significant change in levels was observed. Following, 8 and 16 weeks of supplementation a respectively non-significant and significant reduction of this parameter in the supplemented group compared with the non-supplemented group was revealed.

54.49

48.27 48.67

54.67 ns

59.85 ns

62.31

**

0 40 80

baseline 8 weeks 16 weeks

Values of LPO (µmol/L)

Group three + AS Group three – AS

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Figure 4.2a. Selenium, vitamins C and E supplementation effects on

8-hydroxy-2-deoxyguanosine (8-OHdG) levels at baseline, 8 and 16 weeks in DM subjects without diabetic foot ulcer (Group two)

Group two + AS = Diabetes mellitus subjects without diabetic foot ulcer administered with antioxidant supplementation

Group two – AS = Diabetes mellitus subjects without diabetic foot ulcer not administered with antioxidant supplementation

In this group, there is no significant change in the value of 8-OHdG between the supplemented and non-supplemented of Group two at baseline. Following 8 and 16 weeks of antioxidant supplementation, decreases in values that are non-significant and significant respectively were found when supplemented group were compared with the non-supplemented group.

46.51

43.39 41.77

47.00 ns

53.74 ns

55.12

**

0 40 80

baseline 8 weeks 16 weeks

Values of 8-OHdG (ng/mL)

Group two + AS Group two – AS

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Figure 4.2b. Selenium, vitamins C and E supplementation effects on 8-

hydroxy-2-deoxyguanosine (8-OHdG) levels at baseline, 8 and 16 weeks in DM subjects with diabetic foot ulcer (Group three)

Group three + AS = Diabetes mellitus subjects with diabetic foot ulcer administered with antioxidant supplementation

Group three – AS =Diabetes mellitus subjects with diabetic foot ulcer not administered with antioxidant supplementation

At baseline, 8-OHdG value in non-supplemented diabetic foot ulcer group was found to be lower than the value obtained in the supplemented group (p<0.001). A non-significant decrease at 8 weeks and a significant reduction at 16 weeks (p<0.001) of antioxidant micronutrients supplementation were observed in the supplemented diabetic foot ulcer group when compared with the non-supplemented group

53.55

47.93

41.48 46.37

*

52.15 ns

58.80

*

0 40 80

baseline 8 weeks 16 weeks

Values of 8-OHdG (ng/mL)

Group three + AS Group three – AS

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Figure 4.3a. Selenium, vitamins C and E supplementation effects on

superoxide dismutase (SOD) activities at baseline, 8 and 16 weeks in DM subjects without diabetic foot ulcer (Group two)

Group two + AS = Diabetes mellitus subjects without diabetic foot ulcer administered with antioxidant supplementation

Group two – AS =Diabetes mellitus subjects without diabetic foot ulcer not administered with antioxidant supplementation

The beginning of the study before supplementation, the activities of superoxide dismutase in the supplemented diabetic subjects without ulcer reveal no significant change when compared with the non-supplemented group. Following 8 and 16 weeks of antioxidant supplementation, non-significant increase in activities of this enzyme was found in the supplemented group compared with the non-supplemented group (p>0.05).

3767.79 3862.99 3894.25 3816.24

ns 3678.29

ns

3600.38 ns

0

3000

6000

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