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In order to examine how the initial non-uniformity in the random mixture (Figures 5.1

and 5.5) affects the segregation tendency, an ordered mixture which has a perfectly

uniform concentration distribution was generated in the shoe before die filling. As

shown in Figure 5.22, the ordered mixture is generated by alternately arranging the

mono-sized light and heavy particles in the horizontal and vertical directions. To be

consistent with the previous cases in which the random mixtures are used, die fillings

been simulated. The results show that the overall powder flow patterns with the

ordered mixtures are similar to those with the random mixtures (Figures 5.2, 5.3 and

5.4). The segregation behaviour with the ordered mixtures will be discussed in the

following sections.

Figure 5.22 Configuration of the ordered mixture of the same size but different density particles. (light and heavy particles are coloured in yellow and magenta, respectively)

5.3.1. The effect of shoe velocity

The horizontal concentration distributions of light particles in the die after die filling

with an ordered mixture (ρh / ρl = 19.5) at different shoe velocities are shown in

Figure 5.23. Similar to those with a random mixture (Figure 5.10), significant

segregation with a lower concentration of light particles on the left hand side is

obtained for die filling with a moving shoe at low shoe velocities (i.e. 35 mm/s and 70

mm/s), and no obvious segregation in the horizontal direction is observed for die

filling with a stationary shoe (i.e. 0 mm/s) and with a moving shoe at high shoe

velocities (i.e. 140 mm/s and 170 mm/s). The corresponding vertical concentration

distributions of light particles with the ordered mixture at different shoe velocities are

particles is obtained at the bottom of the die except for die filling with a stationary

shoe, and the concentration of light particles in the die increases as shoe velocity

increases for die filling with a moving shoe. In the presence of air, a lower

concentration of light particles is also observed for die filling with a stationary shoe.

(a) In a vacuum

(b) In air

Figure 5.23 Horizontal concentration distributions of light particles in the die after die filling with an ordered mixture (ρh / ρl = 19.5) at different shoe velocities.

(a) In a vacuum

(b) In air

Figure 5.24 Vertical concentration distributions of light particles in the die after die filling with an ordered mixture (ρh / ρl = 19.5) at different shoe velocities.

Figure 5.25 shows the horizontal and vertical concentration deviations as a function of

shoe velocity for die filling with the ordered mixture. Similarly as obtained from die

filling with the random mixture (Figure 5.12), the larger concentration deviations are

observed for die filling with a moving shoe at low shoe velocities (i.e. vs = 35 mm/s

deviations are observed for die filling with a stationary shoe (vs =0) and with a

moving shoe at higher shoe velocities (i.e. vs = 140 mm/s and 170 mm/s) in which the

bulk-flow dominates. For die filling with a moving shoe, the concentration deviations

generally decrease as shoe velocity increases, but in the presence of air, the horizontal

concentration deviation increases as shoe velocity increases from 140 mm/s to 170

mm/s due to outflow of light particles from the back of the shoe as observed during

die filling with the random mixture (Figure 5.4h).

Figure 5.25 Horizontal and vertical concentration deviations as a function of shoe

velocity for die filling with an ordered mixture (ρh / ρl = 19.5).

5.3.2. The effect of density ratio

Horizontal concentration distributions of light particles in the die after die filling from

a stationary shoe (vs=0) with ordered mixtures of different density ratios are shown in

Figure 5.26. No segregation occurs in the horizontal direction for die filling in a

vacuum. This proves that the horizontal concentration distribution in the die after die

segregation is induced for die filling in the presence of air. The corresponding vertical

concentration distributions of light particles in the die are shown in Figure 5.27. No

vertical segregation occurs for die filling in a vacuum. For die filling in the presence

of air, segregation occurs with a lower concentration of light particles at the bottom of

the die and as the density ratio increases the concentration of light particles at the

bottom of the die initially decreases and then increases.

(a) In a vacuum

(b) In air

Figure 5.26 Horizontal concentration distributions of light particles in the die after die filling from a stationary shoe (vs=0) with ordered mixtures of different density ratios.

(a) In a vacuum

(b) In air

Figure 5.27 Vertical concentration distributions of light particles in the die after die filling from a stationary shoe (vs=0) with ordered mixtures of different density ratios.

Figure 5.28 shows the horizontal and vertical concentration deviations as a function of

density ratio for die filling with ordered mixtures and a stationary shoe. As observed

in die filling with random mixtures (Figure 5.15), the concentration deviations in air

promote the segregation, especially in the vertical direction. For die filling in air, as

the density ratio increases the vertical concentration deviation initially increases due

to the increasing difference in falling velocities of light (air-sensitive) and heavy (air-

inert) particles and then decreases due to the formation of denser powder flow streams

with increasing particle densities.

Figure 5.28 Horizontal and vertical concentration deviations as a function of density

ratio for die filling with ordered mixtures and a stationary shoe.

Horizontal concentration distributions of light particles in the die after die filling with

ordered mixtures of different density ratios at a shoe velocity of 70 mm/s are shown in

Figure 5.29. In general, segregation occurs in the horizontal direction with a lower

concentration of light particles on the left hand side of the die. As the density ratio

increases, the concentration of light particles on the left hand side decreases. The

corresponding vertical concentration distributions are shown in Figure 5.30.

Segregation also occurs in the vertical direction with a lower concentration of light

particles at the bottom of the die. As the density ratio increases, the concentration of

(a) In a vacuum

(b) In air

Figure 5.29 Horizontal concentration distributions of light particles in the die after die

(a) In a vacuum

(b) In air

Figure 5.30 Vertical concentration distributions of light particles in the die after die

filling with ordered mixtures of different density ratios at a shoe velocity of 70 mm/s.

Figure 5.31 shows the horizontal and vertical concentration deviations as a function of

density ratio for die filling with ordered mixtures at a shoe velocity of 70 mm/s. In

general, the concentration deviation increases as the density ratio increases due to the

velocities to segregate from the heavy ones. The effect of air is limited due to the easy

release of the air from the die cavity in nose-flow dominant die filling process. These

findings are also similar to those for the die filling with the random mixtures (Figure

5.18).

Figure 5.31 Horizontal and vertical concentration deviations as a function of density

ratio for die filling with ordered mixtures at a shoe velocity of 70 mm/s.

5.4. Summary

Density-induced segregation during die filling with binary mixtures of mono-sized

particles in air and in a vacuum was investigated using a coupled DEM/CFD method.

Die filling with random mixtures, which were generated by randomly mixing the light

particles (of low particle density) and the heavy particles (of high particle density),

was considered first. The particles of different densities have different air sensitivities

and the difference in air sensitivity was found to have a significant impact on the

For die filling with a stationary shoe, a low degree of segregation is observed in a

vacuum, which is attributed to the non-uniformity of the initial random mixture in the

shoe. When air is present, the entrapped air resists the downward flow of the air-

sensitive particles (the light particles), so that vertical segregation is induced with a

lower concentration of light particles at the bottom of the die. It is also observed that

the air flow can disturb the flowing stream of particles, by which fluctuations of the

horizontal concentration profile are promoted. As the density ratio (ρh / ρl) increases,

the degree of segregation in air initially increases due to the increasing difference in

falling acceleration from the effect of air drag; and then remains nearly constant or

even decreases due to the formation of the denser powder flow stream that suppresses

the segregation.

For die filling with a moving shoe, nose-flow and bulk-flow are observed to dominate

die filling at low and high shoe velocities, respectively. The degree of segregation

generally decreases as the shoe velocity increases with the transition of die filling

from nose-flow dominated to bulk-flow dominated. For nose-flow dominated die

filling, segregation occurs with a depletion of light particles not only at the bottom of

the die but also at the leading side of the die that the shoe moves towards. When nose-

flow occurs, the air can escape from the die before the die opening is completely

covered by the moving powder mass, so that the influence of air on the powder flow

and segregation behaviours is limited for the nose-flow dominated die filling. For

bulk-flow dominated die filling in a vacuum, no obvious segregation occurs in the

horizontal direction and only vertical segregation occurs with a low concentration of

the die by the fast moving powder mass in the shoe, and the entrapped air can cause

an incomplete filling of the die (for low particle density) or the outflow of a lights-rich

stream of particles from the trailing side of the die (referring to the direction of shoe

motion). Consequently, the presence of air could have an impact on the segregation

behaviour during the bulk-flow dominated die filling. It is also found that the degree

of segregation during die filling with a moving shoe increases as the density ratio (ρh /

ρl) increases, due to the increasing difference in inertia of the particles.

Finally, ordered mixtures, which are perfectly uniform, were employed to eliminate

the initial heterogeneity which exists in the random mixtures. The results from die

fillings with the ordered mixtures were in good agreement with those from die fillings

with the random mixtures. This implies that the slight non-uniformity in the randomly

generated mixtures has a negligible effect on the powder flow patterns and

segregation tendency during die filling. Therefore, the density-induced segregation

discussed in this study is a general consequence of die filling with well-mixed binary

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