Análisis de datos y resultados
EL PROCESO TEATRAL COMO DISCURSO POLÍTICO DE LAS VÍCTIMAS Los integrantes comprendieron la importancia del proceso teatral para construir y
Kinetic investigation of the reaction of the ylide 1a with nitrostyrene 7b in DMSO
Table 31: Kinetics of the reaction of 1a with nitrostyrene 7b in DMSO at 20°C (diode array UV-Vis
spectrometer, = 363 nm).
No. [E]0 / mol L-1 [Nu]0 / mol L-1 kobs / s-1 RAK 23.3-2-1 4.16 × 10-5 4.29 × 10-4 2.30 × 10-3 RAK 23.3-2-2 4.86 × 10-5 6.41 × 10-4 3.55 × 10-3 RAK 23.3-2-3 4.90 × 10-5 8.61 × 10-4 4.75 × 10-3 RAK 23.3-2-4 4.88 × 10-5 1.07 × 10-3 5.84 × 10-3 RAK 23.3-2-5 4.79 × 10-5 1.26 × 10-3 6.88 × 10-3 k2 = 5.46 L mol-1 s-1
Determination of the N-Parameter for 1d
(Correlation of log k2 for the Reactions of 1d w ith 2f–k
Versus the Electrophilicity Parameters E for 2f–k)
y = 6.35818E-01x + 1.31052E+01 R2 = 9.98102E-01 0 1 2 3 4 5 6 -20 -18 -16 -14 -12 -10 E lo g k2 y = 5.460E+00x + 6.215E-06 R2 = 9.995E-01 0 0.002 0.004 0.006 0.008 0 0.0004 0.0008 0.0012 0.0016 [Nu] / mol L-1 kobs / s -1
Kinetic investigations of the reactions of the carbanion 1c with the nitrostyrenes 7 in DMSO
Table 32: Kinetics of the reaction of 1c with nitrostyrene 7a in DMSO at 20°C (stopped-flow UV-Vis
spectrometer, = 330 nm).
No. [E]0 / mol L-1 [Nu–]0 / mol L-1 kobs / s-1 RAK 21.9-1 3.76 × 10-5 5.08 × 10-4 5.88 × 10-2 RAK 21.9-2 3.76 × 10-5 7.62 × 10-4 8.90 × 10-2 RAK 21.9-3 3.76 × 10-5 1.02 × 10-3 1.21 × 10-1 RAK 21.9-4 3.76 × 10-5 1.27 × 10-3 1.57 × 10-1 RAK 21.9-5 3.76 × 10-5 1.52 × 10-3 1.83 × 10-1 k2 = 1.25 102 L mol-1 s-1
Table 33: Kinetics of the reaction of 1c with nitrostyrene 7b in DMSO at 20°C (stopped-flow UV-Vis
spectrometer, = 360 nm).
No. [E]0 / mol L-1 [Nu–]0 / mol L-1 kobs / s-1 RAK 21.10-1 3.74 × 10-5 7.62 × 10-4 2.96 × 10-2 RAK 21.10-2 3.74 × 10-5 1.02 × 10-3 4.03 × 10-2 RAK 21.10-3 3.74 × 10-5 1.27 × 10-3 5.08 × 10-2 RAK 21.10-4 3.74 × 10-5 1.52 × 10-3 6.02 × 10-2 RAK 21.10-5 3.74 × 10-5 1.78 × 10-3 7.02 × 10-2 k2 = 3.98 101 L mol-1 s-1
Kinetic investigations of the reactions of the carbanion 1d with the nitrostyrenes 7 in DMSO
Table 34: Kinetics of the reaction of 1d with nitrostyrene 7a in DMSO at 20°C (stopped-flow UV-Vis
spectrometer, = 330 nm).
No. [E]0 / mol L-1 [Nu–]0 / mol L-1 kobs / s-1 RAK 22.8-1 3.96 × 10-5 4.53 × 10-4 4.85 RAK 22.8-2 3.96 × 10-5 6.80 × 10-4 7.77 RAK 22.8-3 3.96 × 10-5 9.07 × 10-4 1.04 × 101 RAK 22.8-4 3.96 × 10-5 1.13 × 10-3 1.32 × 101 RAK 22.8-5 3.96 × 10-5 1.36 × 10-3 1.59 × 101 k2 = 1.21 104 L mol-1 s-1 y = 1.246E+02x - 4.800E-03 R2 = 9.981E-01 0 0.05 0.1 0.15 0.2 0 0.0004 0.0008 0.0012 0.0016 [Nu–] / mol L-1 kob s / s -1 y = 3.982E+01x - 3.300E-04 R2 = 9.994E-01 0 0.025 0.05 0.075 0.1 0 0.0005 0.001 0.0015 0.002 [Nu–] / mol L-1 kobs / s -1 y = 1.214E+04x - 5.880E-01 R2 = 9.998E-01 0 4 8 12 16 0 0.0004 0.0008 0.0012 0.0016 [Nu–] / mol L-1 kobs / s -1
Table 35: Kinetics of the reaction of 1d with nitrostyrene 7b in DMSO at 20°C (stopped-flow UV-Vis
spectrometer, = 360 nm).
No. [E]0 / mol L-1 [Nu–]0 / mol L-1 kobs / s-1 RAK 22.9-1 3.82 × 10-5 4.53 × 10-4 1.63 RAK 22.9-2 3.82 × 10-5 6.80 × 10-4 2.46 RAK 22.9-3 3.82 × 10-5 9.07 × 10-4 3.21 RAK 22.9-4 3.82 × 10-5 1.13 × 10-3 4.03 RAK 22.9-5 3.82 × 10-5 1.36 × 10-3 4.79 k2 = 3.48 103 L mol-1 s-1
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