• No se han encontrado resultados

The matrix model of the TSL base metals converter demonstrated in this study has to a large extent accomplished in predicting the critical process input parameters necessary to produce matte, slag and offgas of desired quality. The model also further discussed the effects of change of operating variables on process inputs requirements and volumes and quality of the outputs. However further work may be required for a complete process representation. To improve on this matrix model, the following is recommended;

• Model validation has been performed through comparison of the matrix model results and the actual plant operating data from one of the smelters. Due to restrictions of change that can be made on the plant, further validation using data from various operations is required to gain complete confidence in the matrix model results.

• The mass and energy balance did not include the dilution air into the process which is a key operating variable in most smelting processes. The effect of dilution air into the furnace environment must be included in future models of the TSL base metal converter. • The temperatures of the product matte, slag and offgas were assumed to be the same,

however in actual plant processes they are at slightly different temperatures hence it is recommended that further modeling must take into consideration the difference in matte, slag and offgas temperatures.

• The mass and heat loss balances used in the model were for the copper crucible of dimensions 4.4m internal diameter and 4.5m height which is situated at the bottom of the TSL furnace where bath process reactions take place. It is recommended that the mass and heat balance equations be expanded on the entire TSL furnace to include the omitted inputs of roof coal, shroud air and oxygen.

University

of Cape

Town

124

References

Alvarado R, Hernandez F, Moya C, Recent developments in the Teniente Converter, Copper 95- Cobre 95, Proceedings of the 3rd International Conference, Volume IV Pyrometallurgy of Copper, The Metallurgical Society of CIM, Montreal, Canada, 1995, p83-101.

Alvarado R, Godoy J, New strategic scope of the Caletons smelter develpment, Proceedings of copper 99- Cobre 99 international Conference, Volume V, Smelting operations and advances, Phoenix, AZ, USA, 1999, p47-55.

Arthur P, Li Y, Yunnan copper corporation’s new smelter- China’s first Isasmelt, Yazawa international symposium on metallurgical and materials processing, Vol II, Warrendale, USA, 2003.

Arthur P, Hunt SP, Isasmelt, 25 years of continuous evolution, Floyd international symposium on sustainable developments in metals processing, Australia 2005, p73-94.

Bakker ML, Isaconvert-Continuous converting of Nickel/PGM mattes, Southern African pyro metallurgical conference, March 2011.

Baldock BR, Short WE, Australian technology on the world scene - Update on Ausmelt plants and projects, MINPREX 2000, International congress on minerals processing and extractive metallurgy, Melbourne 2000, p169-174.

Binegar AH, Cyprus Isasmelt start up and operating experience, Copper 1995, Vol IV, 1995.

Bustos A, Richards GG, Gray NB and Brimacombe J, Injection phenomena in nonferrous processes, Metallurgical Transactions B, 1984.

Campos R and Torres L, Caletones Smelter two decades of technological improvements, Extractive Metallurgy of Copper, Nickel and Cobalt - The Paul E Queneau International Symposium, Vol II, Copper and Nickel Smelter Operations, TMS, Warrendale, Pennsylvania, 1993, p1441- 1460.

Casley GE, Middlin J and White D, Recent developments in reverberatory furnace and converter practice at the Mount lsa Mines copper smelter, Extractive Metallurgy of Copper. Volume I, Py- rometallurgy and Electrolytic Refining, TMS, Warrendale, Pennsylvania, 1976, p117-138.

Davenport WG, Jones DM, King MJ and Partelpoeg EH, Flash Smelting, Analysis Control and Optimization, TMS, Warrendale, Chapters 2, 3, 4, 5, 6, 9, 13, 15, 16 and 17 Pennsylvania, 2001. Davenport WG and Biswas AK, Extractive metallurgy of copper, 4th Edition, Chapters 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 13, 15, 16 and 17, 2002.

Dutton W and Simms D, Automated Gaspe puncher - Process Control and Automation in Extractive Metallurgy, TMS, Warrendale, Pennsylvania, 1988, p131-137.

Edwards JS, Isasmelt- a 250,000tpa copper smelting furnace, AusIMM, Melbourne, 1998. Edwards JS, Jahanshahi S, Copper converting, USA, 1999.

University

of Cape

Town

125 Edwards JS, Alvear GRF, Converting using ISASMELT Technology, Copper 07, Vol. III, Book 2: The Carlos Diaz Symposium on Pyrometallurgy, Metallurgical Society, Toronto, CA, 2007, CIM, Montreal, 2007, pp.17-28.

Edwards JS, Burrows AS, and Alvear GRF, ISACONVERT – TSL Continuous Copper Converting Update, International Peirce-Smith Converting Centennial, TMS 2009 Annual Meeting and Exhibition, The Minerals, Metals & Materials Society, USA, 2009, p407- 414.

Eltringham GA, Johnson RE, Themelis NJ, A survey of worldwide copper converter practices and Copper and Nickel Converters, TMS, Warrendale, Pennsylvania, 1979.

Eltringham GA, Developments in converter fluxing, Converting, Fire Refining and Casting, TMS, Warrendale, 1993, p323- 331.

Eltringham GA, Palabora mining company smelter evaluation, 1993

Eric R, Hejja A, Scale up and operating considerations for six electrode furnaces part I-Current and heat flow in the slag, Procedings1995 EPD, Las Vegas, Warrendale, Pennysvania, 1995, p112- 238.

Errington WG, Edwards JS, Hawkins P, Isasmelt technology-Current status and future developments, SAIMM, 1997.

Fukushima K, Kurokawa H and Yamagiwa M, Development of automation systems for copper converters and anode casting wheel at Toyo smelter, Process Control and Automation in Ex- tractive Metallurgy, TMS, Warrendale, Pennsylvania, 1988, p113- 130.

Garbers A, Introduction to pyrometallurgy, Refractories course notes, University of Pretoria, 2010. Geraldo R, Arthur P, Feasibility to profitability with copper Isasmelt-Copper 2010, Santiago Chile, 2010.

Geraldo R, Alvear F, Burrows A and Nikolic S, Modern Flexible and clean technologies for recovery and recycling of valuable metals- 2nd International workshop on metals recovery from mining wastes, Santiago Chile, 2012.

Harris C, Bath smelling in the Noranda Process Reactor and the El Teniente Process Converter compared, Copper 99-Cobre 99 Proceedings of the 4th International Conference, Volume V, Smelting optimisation and Advances, TMS, Warrendale, PA, 1999, p305- 318.

Hughes S, Journal of metals, 2000.

Jacobs M, Process description and abbreviated history of Anglo Platinum Waterval Smelter, SAIMM conference 2006.

Jones RT, Platinum smelting in South Africa, South African Journal of Science, Vol 95, 1999. Lehner T, Ishikawa O, Smith T, Floyd J, Mackey P, and Landolt C, The 1993 survey of world- wide copper and nickel converter practices, Converting, Fire Refining and Casting, TMS, Warrendale, PA, 1993.

University

of Cape

Town

126 Mackey PJ and Harris C, Levac C, Continous converting of matte in the Noranda Converter, Part I and II, Plant evaluation and metallurgical gackground, Proceeding of copper 95- Combre 95 inter- national conference, Santiago, Chile 1995, p337- 366

Mackey PJ, Pannell DG, Noranda process operations 1988 and future trends, GDNB, Antwerp, Belgium, 1988

Mackey PJ and Campos R, Modern continuous smelting and converting by bath smelting tech- nology, Canadian metallurgical Quarterly, 2001.

Mill K, The estimation of slag properties, Southern African pyrometallurgical conference, March 2011.

Mills K, Structure of liquid slags, In Eisenhuttenleute, V.D (Ed), Slag Atlas, 2nd edition, Verlag stahleisen GmbH, 1995.

Maruyama T, Saito T and Kato M, Improvements of the converter's operation at Tamano smelter, Sulfide Smelting 98, TMS, Warrendale, Pennsylvania, 1998, p219- 227.

Matthews S, personal communication on the TSL Ni-Cu- Fe -PGM converter operations and process parameters, 2009.

Matusewicz R, Sofra J, Ausmelt Technology developments in copper converting proceedings of EMC, Dresden GDMB, German, 2005, p21 -32.

Matusewicz R, Sofra J, Ausmelt technology- Copper production technology for the 21st century, copper 2003, Santiago, Chile, Vol IV, 2003, p157-172.

Mounsey EN, Li H and Floyd JW, (1999) The design of the Ausmelt technology smelter at Zhong Tiao Shan Houma smelter, People's Republic of China, Copper 99- Cobre 99, Proceedings of the 4th International Conference, Vol V, Smelting Operations and Advances, TMS, Warren- dale, PA, 1999, p357- 370.

Nell J, Smelting of platinum group metals concentrates in South Africa, JOM SAIMM, 2004.

Nelson L, Geldenhuis J, Hatch development in furnace design in conjunction with smelting plants in Africa, SAIMM, 2006.

Pelletier A and Mackey PJ, The Noranda tuyere pyrometer - A new approach to furnace temperature measurement. In Copper 87, Vol IV, Pyrometallurgy of Copper, Santiago, Chile, 1987, p375- 391.

Richards G and Jorgensen D, Bath slopping and splashing in the copper converter, Reinhardt Schuhmann International Symposium on Innovative Technology and Reactor Design in Extraction Metallurgy, TMS, Warrendale, Pennsylvania, 1986, p385- 402.

University

of Cape

Town

127 Ross J, Mufulira smelter upgrade project- Industry smelting on the Zambian copperbelt, Pyrometallurgy 2005, Capetown, Minerals engineering international.

Rutanen J, Water cooled Freeboard and uptake for Ausmelt converters, ACP Project system speci- fications, 2001.

Schonewille RH, O'Connell GJ and Toguri JM, A quantitative method for silica flux evaluation. Metallurgical Transactions B, 1993.

Sharma SN, Jimenez RA, Ogilive KM and Hansen AH, (1979) Control of secondary emissions from copper converters, Copper and Nickel Converters, TMS, Warrendale, Pennsylvania, 1979, p312- 335

Shimpo R, Ogawa O and Asakura I, A study on the equilibrium between copper matte and slag, Canada Metallurgy quarter, 1996.

Shook A and Eltringham GA, Online SO2 analysis of copper converter off-gas, Copper 99-

Cobre 99 Proceedings of the 4th International Conference, Vol. V, Smelting Operations and Advances, TMS, Warrendale, PA, 1999, p465- 475.

Hyrn JN, Toguri JM, Choo RTC and Stubina NM, Densities of molten copper-nickel sulphide mattes between 1100-1300oC, Canadian metallurgical quarterly, Vol 35, 1996, p123-132.

Torres WE, Current Teniente Converter practice at the SPL Ilo smelter, Sulphide smelting 98, Current and future practices, TMS, Warrendale, 1998.

Turkdogan ET, Physicochemistry properties of molten slags and glasses, The metals society, ISBN 0 904357 54 6, 1983.

Utigard TA, Density of copper/nickel sulphide smelting and converting slags, Scandinavia JM, 1994, p23-41.

Utigard TA, and Warczok, Density and viscosity of copper/nickel sulphide smelting and converting slags, Copper 95, Proceedings of the Third International Conference, Vol. IV Pyrometallurgy of Copper, The Metallurgical Society of CIM, Montreal, Canada, 1995, p423-437.

Verney LR, Peirce-Smith copper converter operations and economics, Copper 87, Vol IV, Pyrometallurgy of Copper, Santiago, Chile, 1987, p375- 391.

Wicks JN, Smelter and converter practice at Waterval smelter- Process challenges and innovations, Process developments in non ferrous metallurgy, SAIMM, Cape Town, South Africa, 2000.

Winston W, Ventakataramanan M, Introduction to mathematical programming, 2003

Yazawa K, and Kameda A, Copper smelting systems, Technology Rep, Tohoku University, 1953. Yazawa A, Takeda Y, Nakazawa S, Thermodynamics of calcium ferrite slags at 1200 and 1300oC, Canada metallurgy, Vol 19, 1980, p297-305.

Yazawa A, Takeda Y, Thermodynamic properties and structure of ferrite slags and their implications, Canada metallurgy, Quebec, Vol 20, 1981, p29-34.

University

of Cape

Town

128 Yazawa A, Takeda Y, Ferrous calcium silicate slag to be used for copper smelting and converting, Copper 1999 – Vol IV, Phoenix, USA, 1999.

Yazawa A, Takeda Y, Liquidus relations of Calcium ferrite and ferrous calcium silicate slag in copper continuous converting, Sohn international symposium, San Diego, USA, TMS, 2006.

University

of Cape

Town

129

Appendices

Appendix 1.0 Stoichiometric data for elements, minerals and