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Chemistry 5.04 (F08) Problem Set 1 addendum

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MIT OpenCourseWare http://ocw.mit.edu

5.04 Principles of Inorganic Chemistry II

Fall 2008

For information about citing these materials or our Terms of Use, visit: http://ocw.mit.edu/terms.

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Chemistry 5.04 (F08) Problem Set 1 addendum

Due Friday, 19 September

1. Assign point groups to the following molecules. Sketch the molecule and the symmetry elements present in each.

a. ethane (staggered) b. ethane (eclipsed) c. cyclohexane (chair) d. cyclohexane (boat) e. adamantane

f. ferrocene (staggered) g. ferrocene (eclipsed) h. P4

i. S8

2. Draw a molecule (not found in the texts or lecture notes) that exemplifies each of the following point groups. Please use molecules that actually exist.

a. C2h

b. D8h

c. D2d

d. CS

e. C6v

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