The Present

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The supplementary material contains: I. Filter-Based Thermal Desorption System; II.

Per-474

formance of F-TD; III. Sample Generation; IV. Data Analysis; V. Isothermal Evaporation;

475

VI. Thermograms; VII. Identified Main Compounds from UPLC/ESI-MS; VIII.

Decompo-476

sition of Hydroperoxides.

477

References

478

(1) George, I. J.; Abbatt, J. P. D. Heterogeneous oxidation of atmospheric aerosol particles

479

by gas-phase radicals. Nat. Chem. 2010, 2, 713.

480

(2) Reid, J. P.; Bertram, A. K.; Topping, D. O.; Laskin, A.; Martin, S. T.; Petters, M. D.;

481

Pope, F. D.; Rovelli, G. The viscosity of atmospherically relevant organic particles. Nat.

482

Commun. 2018, 9, 956.

483

(3) Chow, J. C.; Yu, J. Z.; Watson, J. G.; Ho, S. S. H.; Bohannan, T. L.; Hays, M. D.;

484

Fung, K. K. The application of thermal methods for determining chemical composition

485

of carbonaceous aerosols: A review. J. Environ. Sci. Health A 2007, 42, 1521–1541.

486

(4) Cappa, C. D. A model of aerosol evaporation kinetics in a thermodenuder. Atmos.

487

Meas. Tech. 2010, 3, 579–592.

488

(5) Schobesberger, S.; D’Ambro, E. L.; Lopez-Hilfiker, F. D.; Mohr, C.; Thornton, J. A. A

489

model framework to retrieve thermodynamic and kinetic properties of organic aerosol

490

from composition-resolved thermal desorption measurements. Atmos. Chem. Phys.

491

2018, 18, 14757–14785.

492

(6) Hearn, J. D.; Smith, G. D. A chemical ionization mass spectrometry method for the

493

online analysis of organic aerosols. Anal. Chem. 2004, 76, 2820–2826.

494

(7) Smith, J. N.; Moore, K. F.; McMurry, P. H.; Eisele, F. L. Atmospheric measurements

495

of sub-20 nm diameter particle chemical composition by thermal desorption chemical

496

ionization mass spectrometry. Aerosol Sci. Technol. 2004, 38, 100–110.

497

(8) DeCarlo, P. F.; Kimmel, J. R.; Trimborn, A.; Northway, M. J.; Jayne, J. T.;

498

Aiken, A. C.; Gonin, M.; Fuhrer, K.; Horvath, T.; Docherty, K. S.; Worsnop, D. R.;

499

Jimenez, J. L. Field-deployable, high-resolution, time-of-flight aerosol mass

spectrome-500

ter. Anal. Chem. 2006, 78, 8281–8289.

501

(9) Huffman, J. A.; Ziemann, P. J.; Jayne, J. T.; Worsnop, D. R.; Jimenez, J. L.

Develop-502

ment and characterization of a fast-stepping/scanning thermodenuder for

chemically-503

resolved aerosol volatility measurements. Aerosol Sci. Technol. 2008, 42, 395–407.

504

(10) Cappa, C. D.; Wilson, K. R. Evolution of organic aerosol mass spectra upon heating:

505

implications for OA phase and partitioning behavior. Atmos. Chem. Phys. 2011, 11,

506

1895–1911.

507

(11) Tobias, H. J.; Ziemann, P. J. Compound identification in organic aerosols using

508

temperature-programmed thermal desorption particle beam mass spectrometry. Anal.

509

Chem. 1999, 71, 3428–3435.

510

(12) Yatavelli, R. L. N.; Thornton, J. A. Particulate organic matter detection using a

511

micro-orifice volatilization impactor coupled to a chemical ionization mass spectrometer

512

(MOVI-CIMS). Aerosol Sci. Technol. 2010, 44, 61–74.

513

(13) Lopez-Hilfiker, F. D.; Mohr, C.; Ehn, M.; Rubach, F.; Kleist, E.; Wildt, J.;

514

Mentel, T. F.; Lutz, A.; Hallquist, M.; Worsnop, D.; Thornton, J. A. A novel method

515

for online analysis of gas and particle composition: description and evaluation of a filter

516

inlet for gases and aerosols (FIGAERO). Atmos. Meas. Tech. 2014, 7, 983–1001.

517

(14) Williams, B. J.; Goldstein, A. H.; Kreisberg, N. M.; Hering, S. V. In situ measurements

518

of gas/particle-phase transitions for atmospheric semivolatile organic compounds. Proc.

519

Natl. Acad. Sci. U.S.A. 2010, 107, 6676–6681.

520

(15) Isaacman, G.; Kreisberg, N. M.; Yee, L. D.; Worton, D. R.; Chan, A. W. H.; Moss, J. A.;

521

Hering, S. V.; Goldstein, A. H. Online derivatization for hourly measurements of

gas-522

and particle-phase semi-volatile oxygenated organic compounds by thermal desorption

523

aerosol gas chromatography (SV-TAG). Atmos. Meas. Tech. 2014, 7, 4417–4429.

524

(16) Yatavelli, R. L. N.; Stark, H.; Thompson, S. L.; Kimmel, J. R.; Cubison, M. J.;

525

Day, D. A.; Campuzano-Jost, P.; Palm, B. B.; Hodzic, A.; Thornton, J. A.; Jayne, J. T.;

Worsnop, D. R.; Jimenez, J. L. Semicontinuous measurements of gas-particle

partition-527

ing of organic acids in a ponderosa pine forest using a MOVI-HRToF-CIMS. Atmos.

528

Chem. Phys. 2014, 14, 1527–1546.

529

(17) D’Ambro, E. L.; Schobesberger, S.; Zaveri, R. A.; Shilling, J. E.; Lee, B. H.;

Lopez-530

Hilfiker, F. D.; Mohr, C.; Thornton, J. A. Isothermal evaporation of α-pinene ozonolysis

531

SOA: volatility, phase state, and oligomeric composition. ACS Earth Space Chem.

532

2018, 2, 1058–1067.

533

(18) Huang, W.; Saathoff, H.; Pajunoja, A.; Shen, X.; Naumann, K.-H.; Wagner, R.;

Virta-534

nen, A.; Leisner, T.; Mohr, C. α-Pinene secondary organic aerosol at low temperature:

535

chemical composition and implications for particle viscosity. Atmos. Chem. Phys. 2018,

536

18, 2883–2898.

537

(19) Steiner, T. The hydrogen bond in the solid state. Angew. Chem. Int. Ed. 2002, 41,

538

48–76.

539

(20) Stark, H.; Yatavelli, R. L. N.; Thompson, S. L.; Kang, H.; Krechmer, J. E.;

Kim-540

mel, J. R.; Palm, B. B.; Hu, W.; Hayes, P. L.; Day, D. A.; Campuzano-Jost, P.;

541

Canagaratna, M. R.; Jayne, J. T.; Worsnop, D. R.; Jimenez, J. L. Impact of thermal

542

decomposition on thermal desorption instruments: advantage of thermogram analysis

543

for quantifying volatility distributions of organic species. Environ. Sci. Technol. 2017,

544

51, 8491–8500.

545

(21) Zhao, Z.; Yang, X.; Lee, J.; Tolentino, R.; Mayorga, R.; Zhang, W.; Zhang, H. Diverse

546

Reactions in Highly Functionalized Organic Aerosols during Thermal Desorption. ACS

547

Earth Space Chem. 2020, 4, 283–296.

548

(22) Willoughby, A. S.; Wozniak, A. S.; Hatcher, P. G. A molecular-level approach for

549

characterizing water-insoluble components of ambient organic aerosol particulates using

550

ultrahigh-resolution mass spectrometry. Atmos. Chem. Phys. 2014, 14, 10299–10314.

551

(23) Kenseth, C. M.; Hafeman, N. J.; Huang, Y.; Dalleska, N. F.; Stoltz, B. M.;

Sein-552

feld, J. H. Synthesis of carboxylic acid and dimer ester surrogates to constrain the

553

abundance and distribution of molecular products in α-pinene and β-pinene secondary

554

organic aerosol. Environ. Sci. Technol. submitted.

555

(24) Crounse, J. D.; McKinney, K. A.; Kwan, A. J.; Wennberg, P. O. Measurement of

gas-556

phase hydroperoxides by chemical ionization mass spectrometry. Anal. Chem. 2006,

557

78, 6726–6732.

558

(25) St. Clair, J. M.; McCabe, D. C.; Crounse, J. D.; Steiner, U.; Wennberg, P. O. Chemical

559

ionization tandem mass spectrometer for the in situ measurement of methyl hydrogen

560

peroxide. Rev. Sci. Instrum. 2010, 81, 094102.

561

(26) Paulot, F.; Crounse, J. D.; Kjaergaard, H. G.; K¨urten, A.; Clair, J. M. S.; Seinfeld, J. H.;

562

Wennberg, P. O. Unexpected epoxide formation in the gas-phase photooxidation of

563

isoprene. Science 2009, 325, 730–733.

564

(27) Huang, Y.; Coggon, M. M.; Zhao, R.; Lignell, H.; Bauer, M. U.; Flagan, R. C.;

Sein-565

feld, J. H. The Caltech photooxidation flow tube reactor: design, fluid dynamics and

566

characterization. Atmos. Meas. Tech. 2017, 10, 839–867.

567

(28) Kenseth, C. M.; Huang, Y.; Zhao, R.; Dalleska, N. F.; Hethcox, J. C.; Stoltz, B. M.;

568

Seinfeld, J. H. Synergistic O₃ + OH oxidation pathway to extremely low-volatility

569

dimers revealed in β-pinene secondary organic aerosol. Proc. Natl. Acad. Sci. U.S.A.

570

2018, 115, 8301–8306.

571

(29) Zhao, R.; Kenseth, C. M.; Huang, Y.; Dalleska, N. F.; Seinfeld, J. H.

Iodometry-572

assisted liquid chromatography electrospray ionization mass spectrometry for analysis

573

of organic peroxides: an application to atmospheric secondary organic aerosol. Environ.

574

Sci. Technol. 2018, 52, 2108–2117.

575

(30) Zhang, X.; McVay, R. C.; Huang, D. D.; Dalleska, N. F.; Aumont, B.; Flagan, R. C.;

576

Seinfeld, J. H. Formation and evolution of molecular products in α-pinene secondary

577

organic aerosol. Proc. Natl. Acad. Sci. U.S.A. 2015, 112, 14168–14173.

578

(31) Cappa, C. D.; Lovejoy, E. R.; Ravishankara, A. R. Determination of evaporation rates

579

and vapor pressures of very low volatility compounds: a study of the C₄-C₁₀ and C₁₂

580

dicarboxylic acids. J. Phys. Chem. A 2007, 111, 3099–3109.

581

(32) Emanuelsson, E. U.; Watne, ˚A. K.; Lutz, A.; Ljungstr¨om, E.; Hallquist, M. Influence

582

of humidity, temperature, and radicals on the formation and thermal properties of

583

secondary organic aerosol (SOA) from ozonolysis of β-pinene. J. Phys. Chem. A 2013,

584

117, 10346–10358.

585

(33) Lopez-Hilfiker, F. D.; Mohr, C.; Ehn, M.; Rubach, F.; Kleist, E.; Wildt, J.;

586

Mentel, T. F.; Carrasquillo, A. J.; Daumit, K. E.; Hunter, J. F.; Kroll, J. H.;

587

Worsnop, D. R.; Thornton, J. A. Phase partitioning and volatility of secondary

or-588

ganic aerosol components formed from α-pinene ozonolysis and OH oxidation: the

589

importance of accretion products and other low volatility compounds. Atmos. Chem.

590

Phys. 2015, 15, 7765–7776.

591

(34) Liu, P.; Li, Y. J.; Wang, Y.; Gilles, M. K.; Zaveri, R. A.; Bertram, A. K.; Martin, S. T.

592

Lability of secondary organic particulate matter. Proc. Natl. Acad. Sci. U.S.A. 2016,

593

113, 12643–12648.

594

(35) Yasmeen, F.; Vermeylen, R.; Szmigielski, R.; Iinuma, Y.; B¨oge, O.; Herrmann, H.;

595

Maenhaut, W.; Claeys, M. Terpenylic acid and related compounds: precursors for

596

dimers in secondary organic aerosol from the ozonolysis of α- and β-pinene. Atmos.

597

Chem. Phys. 2010, 10, 9383–9392.

598

(36) Yasmeen, F.; Vermeylen, R.; Maurin, N.; Perraudin, E.; Doussin, J.-F.; Claeys, M.

599

Characterisation of tracers for aging of α-pinene secondary organic aerosol using

liq-600

uid chromatography/negative ion electrospray ionisation mass spectrometry. Environ.

601

Chem. 2012, 9, 236–246.

602

(37) Kolesar, K. R.; Chen, C.; Johnson, D.; Cappa, C. D. The influences of mass loading

603

and rapid dilution of secondary organic aerosol on particle volatility. Atmos. Chem.

604

Phys. 2015, 15, 9327–9343.

605

(38) Hall IV, W. A.; Johnston, M. V. The thermal-stability of oligomers in alpha-pinene

606

secondary organic aerosol. Aerosol Sci. Technol. 2012, 46, 983–989.

607

(39) Claflin, M. S.; Ziemann, P. J. Thermal desorption behavior of hemiacetal, acetal, ether,

608

and ester oligomers. Aerosol Sci. Technol. 2019, 53, 473–484.

609

(40) Docherty, K. S.; Wu, W.; Lim, Y. B.; Ziemann, P. J. Contributions of organic peroxides

610

to secondary aerosol formed from reactions of monoterpenes with O₃. Environ. Sci.

611

Technol. 2005, 39, 4049–4059.

612

(41) Eddingsaas, N. C.; Loza, C. L.; Yee, L. D.; Seinfeld, J. H.; Wennberg, P. O. α-pinene

613

photooxidation under controlled chemical conditions - Part 1: Gas-phase composition

614

in low- and high-NO_x environments. Atmos. Chem. Phys. 2012, 12, 6489–6504.

615

(42) Lopez-Hilfiker, F. D.; Iyer, S.; Mohr, C.; Lee, B. H.; D’Ambro, E. L.; Kurt´en, T.;

616

Thornton, J. A. Constraining the sensitivity of iodide adduct chemical ionization mass

617

spectrometry to multifunctional organic molecules using the collision limit and

ther-618

modynamic stability of iodide ion adducts. Atmos. Meas. Tech. 2016, 9, 1505–1512.

619

(43) Pagonis, D.; Ziemann, P. J. Chemistry of hydroperoxycarbonyls in secondary organic

620

aerosol. Aerosol Sci. Technol. 2018, 52, 1178–1193.

621

(44) Batakliev, T.; Georgiev, V.; Anachkov, M.; Rakovsky, S.; Zaikov, G. E. Ozone

decom-622

position. Interdiscip. Toxicol. 2014, 7, 47–59.

623

(45) Krapf, M.; El Haddad, I.; Bruns, E. A.; Molteni, U.; Daellenbach, K. R.; Pr´evˆot, A.

624

S. H.; Baltensperger, U.; Dommen, J. Labile Peroxides in Secondary Organic Aerosol.

625

Chem 2016, 1, 603–616.

626

(46) Tritscher, T.; Dommen, J.; DeCarlo, P. F.; Gysel, M.; Barmet, P. B.; Praplan, A. P.;

627

Weingartner, E.; Pr´evˆot, A. S. H.; Riipinen, I.; Donahue, N. M.; Baltensperger, U.

628

Volatility and hygroscopicity of aging secondary organic aerosol in a smog chamber.

629

Atmos. Chem. Phys. 2011, 11, 11477–11496.

630

(47) Donahue, N. M.; Henry, K. M.; Mentel, T. F.; Kiendler-Scharr, A.; Spindler, C.;

631

Bohn, B.; Brauers, T.; Dorn, H. P.; Fuchs, H.; Tillmann, R.; Wahner, A.; Saathoff, H.;

632

Naumann, K.-H.; M¨ohler, O.; Leisner, T.; M¨uller, L.; Reinnig, M.-C.; Hoffmann, T.;

633

Salo, K.; Hallquist, M.; Frosch, M.; Bilde, M.; Tritscher, T.; Barmet, P.; Praplan, A. P.;

634

DeCarlo, P. F.; Dommen, J.; Pr´evˆot, A. S. H.; Baltensperger, U. Aging of biogenic

sec-635

ondary organic aerosol via gas-phase OH radical reactions. Proc. Natl. Acad. Sci. U.S.A.

636

2012, 109, 13503–13508.

637

In document 2.2. El aprendizaje de la gramática del inglés (página 126-133)