ANEXO IV: MECANISMOS DE ENTRECRUZAMIENTO
IV.2 Mecanismo ATES
El uso de este agente químico es una metodología de 2 pasos. Primeramente el ATES se injerta en la cadena polimérica vía sustitución nuclofílica y, posteriormente, en una segunda etapa, se produce el entrecruzamiento en presencia de humedad.
CH3 CH3 CH3 CH3
CH 'tV cW ...
¿ ¿2
pvC
u
Aminos&e H20
DI
CH2H2 C
H2 CH2-' 'CH' 'CH'
¿2
L ¿2
cHo----ccH2
LH
Figura IV.2. Sistema de entrecruzamiento propuesto para el ATES
BIBLIOGRAFIA.
Oliverio S. Rodríguez Fernández, I.G.Y.F., Rebeca Betancourt Galindo, Luis Alfonso García Cerda y Carlos Alberto Rodríguez Calzadiaz, Composición de plastisol magnético y método de preparación, in MX/a/2007/0 165292007: Mexico.
Berins, M.L., P/astics Eng/neering Handbook of the Society of the Plast/cs /ndustry. Fifth ed1991: Kluwer Academia Publishers.
Mark, H.F., Encyclopedia ofPolymerScienceand Technology. 3a ed. Vol. 8. 2003: Wiley Interscience.
Rosensweig, R.E., Ferrohydrodynamicslg85: Dover Publications.
Papell, S.S., 1965: EUA.
B.M. Berkovsky, V.F.M., M.S. Krokov, Magnet/c Fluids: Engineering Applicationsl 993: Oxford University Press.
S.G. Grancharov, H.Z., S. Sun, S.X. Wang, S. O'Brien, C.B. Murray, J.R. Kirtley and G.A. HeId, J. Phys.
Chem, 2005. B( 109) : p. 13030-1 3035.
Reimers, K.a., 1974: EUA.
y 5 ABRAHAM, S.S.N., 5 RAJESH, U 5 SAJEEV and M R ANANTHARAMAN, Magnetic fleld induced assemb/ing of nanoparticles in ferrofluidic liquid thin films based on N,)cFel 'xFe2O4. Bull. Mater. Sci, 2004.
27( 2) :p.155-161.
Kimura, H., F. Takada, and W.N. Myung, Amorphization of cobalt-rich magnetic aioys by hih energy bail mihing. Materials Science and Engineering, 1988. 97( 0) : p. 125-128.
Alvarez, P.G., P.; Franco, y.; et al., Nanocrysta/ilne Nd( 2) Fe( 17) synthesizedby hígh-energy bali mill/ng:
crystal structure, microstructure and magnetic properties. Journal of Physics-Condensed Matter, 2010.
22( 21)
Muñoz, J., et al., Iron nanopar/icles producedby high-energy bali miIilng. Journal of Nanoparticle Research, 2007. 9( 5) :p. 945-950.
Elmore, WC., Ferromagnetic Coioid for Studying Magnetic Siructures. Physical Review, 1938. 54( 4) : p.
309-3 10.
Reimers, K.G.W., 1973: EUA.
G. Yáñez-Flores, R.B.-G., J.A. Matutes Aquino and O. Rodríguez-Fernández;, Prepara/ion and characterizat/on of magnetic PVC nanocomposites. Journal of Non-Crystalline Solids, 2007. 353( 8-10) : p.
799-801.
Reimers, K.G.W., Preparation of dilut/on-stab/e aqueous magnefic tluids. IEEE Transactions on Magnetics, 1980. 16( 2) : p. 178-183.
Rabinow, J., The Magnetic Fluid Clutch. AlEE Transactions, 1948. 68: p. 1308-1315.
E.
Skjeltorp, A.T. One- and Two-Oiínensíona/ Crysta//izalion of Magnetic Ho/es. Physical Review Letters, 1983.
51( 25) :p. 2306-2309.
de Gans, B.J., et al. Linear viscoe/asticity oían inverse ferrofluid. Physical Review E, 1999. 60( 4) p. 4518- 4527.
Popplewell, J., R.E. Rosensweig, and J.K. Siller, Magnetorheo/ogy of ferrofluid composites. Journal of Magnetism and Magnetic Materials, 1995. 149( 1 2) : p. 53-56.
B. J. de Gans, N.J.D., D. van den Ende, and J. Mellerna The influence of partic/e s,ze on the magnetorheo/ogicalproperties of an inverse ferrofluid Journal of Chemical Physics, 1999. 113( 5) : p. 2032- 2042.
Gans, B.J.d., et al., Prepara/ion and magnetisation of a si/ica-magnetite inverse ferrofluid. Journal of Magnetism and Magnetic Materials, 1999. 201( 1 3) : p. 11-13.
A.lnoue, SM., Y.lde, H.Oda, Properties of ER F/uids Comprised of Liquid C,ysta/fine Polymers. International Journal of Modern Physics B ( IJMPB) , 1999. 13( 14-16) : p. 1966-1974.
H.Orihara, MD., Y.lshibashi, Two Types of Mechan/sm of E/ectrorheo/ogica/ Effecf in Po/ymer Biends.
International Journal of Modern Physics 8, 1999. 13( 14-16) : P. 1949-1955.
Ginder, J., Nichois, M. El ie, L. ,Tardiff,J, Magnetorheo/ogica/e/astomers.propertiosandapp/icafions.
ProceedingsoftheSPlE, 1999. 3675: p. 131-138.
G. Bossis, C.A., S. Cutillas, S. Lacis, C. Metayer, ELECTROACTIVE ANO ELECTROSTRUCTURED EL4STOMERS. International Journal of Modern Physics B, 2001. 15( 6-7) : p. 564-573.
JoIly, MR., et al., The Magnetoviscoe/astic Response of E/astomer Composites Consisting of Ferrous Parlicles Embedded in a Po/ymer Matriz. Journal of lntelligent Material Systems and Structures, 1996. 7( 6) p. 61 3-622.
Rodríguez-Fernández, OS., et al., Prepara/ion and charactenzation oía magneto-po/ymeric nanocomposite:
Fe304 nanoparticies in a grafled, cross-/inked and plasticized po/y( vinyl chioríde) ma/rA. Journal of Magnetism and Magnetic Materials, 2008. 320( 14) : p. e81-e84.
Saldivar-Guerrero, R., et al., Vfscoe/asticity of mono- and po/ydisperse inverse ferrofluids. The Journal of Chemical Physics, 2006. 125( 8) : p. 084907.
Saldivar-Guerrero, R.R., R.; Rehberg, 1.; Aksel, N.; Heymann, L.; Rodriguez-Fernández, OS, So/id/o 1/quid transitionofinverseferrofluidsunders/iear. Magnetohydrodynamics, 2005. 41( 4) : p. 385-389.
al, Se., Nanomechanics of carbon nanotubes and composites. Appl Mech Rey, 2003. 56( 215-229) Thostenson, E.T., Ren, Z. and Chou,T.W., Advanced in the science and techno/ogy of carbon nanotubes and
their composifes: areview. Composites Science and Technology, 2001. 61: p. 1899-1912.
Anton, 1., 1. de Sabata, and L. Vékás, Applicat/on or/entated researches on magnetic /luids. Journal of Magnetism and Magnetic Materials, 1990. 85( 1 3) : p. 219-226.
Ma, R., Bando, Y., Mori, T. & Golberg, D/rect pyro/ysis method for superconducting crystal/ine MgB2 nanowires. Chem. Mater, 2003. 15: p. 3194-31 97.
Sun, S. and H. Zeng, S,e-Contro//ed Synthesis of Magnetite Nanoparticles. Journal of the American Chemical Society, 2002. 124( 28) : p. 8204-8205.
Catz, H.S.M., Handbookoffillersandreinforcementsforplasticsl989: Van Nostrand Reinhoid Company.
M, Z., Magnetic-fie/d-sens/t/vepolymerge/s. TRENOS IN POLYMER SCIENCE, 1997. 5: p. 280-285.
D.Jilies, Introduction to Magnetisn and Magnetic Materia/s1998: Chapman & Hall.
Handley, ROO., Modern Magnetic Materials: Princ,les andAppficat/ons2000: Wiley & Sons, Inc.
J.L. Dormann, D.F., and E. Tronc, Magnetic Relaxation In Fine-Part/c/e Systemsl 997: John Wiley & Sons, Inc.
E. Garcia Taranjo, A.G.A., S. Garcia Garcia and J. L. Sanchez Llamazares, Metodos Experimentales de Magnetismol 986: Editorial Pueblo y Educacion.
Neuberger, T., et al., Superparamagnet/c nanoparticles for biomedical apphcations: Poss/bllit/es and /imitations of a new drug de//very system. Journal of Magnetism and Magnetic Materials, 2005. 293( 1) : p.
483-496.
Ziolo, R.F., 1997: EUA.
Cumbal, L., el al., Polymer supported inorgan/c nanopart/c/es: characterization and en vironmental applications. Reactive and Functional Polymers, 2003. 54( 1 3) : p. 167-180.
Callister, W.D., Materials Science and Engineering.Anlntroduct/on. 3a ed1997: Wiley.
Rigbi, Z. and J.E. Mark, Effects of a magnetic fleld appfied during the curing of a po/ymer loaded wifh magnetic fi/ter. Journal of Polymer Science: Polymer Physics Edition, 1985. 23( 6) : p. 1267-1269.
Bossis, C.B.a.G., FIELO DEPENDENCE OF VISCOELASTIC PROPERTIES OF MR ELASTOMERS.
International Journal of Modern Physics B, 2002. 16( 17-18) : p. 2447-2453.
Coquelle, E. and G. Bossis, Mulllns effect /n elastomers ti//ed w,ih particles aligned by a magnetic fleld.
International Journal of Solids and Structures, 2006. 43( 25 26) : p. 7659-7672.
Coquelle, E., et al., Micromechan/cal ana/ys/s of an elastomer ñl/ed wllh particles organ,ed in chain-1,ke structure. Journal of Materials Science, 2006. 41( 18) : p. 5941-5953.
Carlson, J.D. and M.R. Jolly, MR fluid, foam and etastomerdev/ces. Mechatronics, 2000. 10( 4 5) : p. 555- 569.
Abramchuk, S., et al., Novel highly elastic magnetic mater/als for dampers and seals: part II. Material behavior /namagneticfie/d. Polymers forAdvanced Technologies, 2007. 18( 7) : p. 513-518.
Milsumata, T., el al., Magnet/sm and compressive modulus of magnetic fluid contain/ng gels. Journal of Applied Physics, 1999. 85( 12) : p. 8451-8455.
Shen, Y., M.F. Golnaraghi, and G.R. Heppler, Experimental Research and Modehng of Magnetorheologica/
Elastomers. Journal of lntelligent Material Systems and Structures, 2004. 15( 1) : p. 27-35.
Jacobo, S. E., et al., /nfluence of the preparation procedure on (he properties of po/yaro/me based magnetic
compos/tes. European Polymer Journal, 2007. 43( 4) p. 1333-1346.
Wang, Y., el al., Preparation and properties of magnetorheo/og/ca/ elastomers based on sificon
rubber/po/ystyrene biend matr,x. Journal of Applied Polymer Science, 2007. 1 03( 5) : p. 3143-3149.
Breval, E., el al., Magnetic ahgnmen( of particles ü, campos/te fi/ms. Journal of Materials Science, 2003.
38( 6) :p. 1347-1351.
Camponeschi, E., el al., Properties of carbon nanotube 'po/ymer composites ahqned in a magnetic ficid.
Carbon, 2007. 45( 10) : p. 2037-2046.
Stepanov, GV., el al., Effect of a homogeneous magnetic field on Ihe viscoe/ast/c behavior of magnetic
elastomers. Polymer, 2007. 48( 2) : p. 488-495.
Zhao, W., el al., Facile preparation of epoxy-based composite with oriented graphite nanosheets. Polymer, 2006. 47( 26) p. 8401-8405.
Newton; Mike, D.J.P., Breval; Else, Klimkiewicz; Maria, Shi; Yi Ton, Method for producing anisotrop/c diete ctr/c /ayer and dey/ces inc/ud/ng same, 2002: EUA.
- 61. Schwertmann, U., Iran oxides in (he laboratory : preparation and character,afion, ed. R.M. CornellI 991, Weinheim ;: VCH.
Chantrell R. W., P., J. and Charles S. W, Measurements of particle s/ze distribution parameters ¡n ferrotluids.
IEEE Transaclions on Magnelics, 1978. 14( 5) : p. 975-977.
Ozkaya, T., el al., Synthesis of Fe304 nanoparticles at lOO
ü; C and /ts magnetic characterization.
Journal of Alloys and Compounds, 2009. 472( 1 2) : p. 18-23.
Kaiser, R. and G. Miskolczy, Magnetic Properties of Stab/e Dispersions of Subdomamn Magnetite Particles.
Journal of Applied Physics, 1970. 41( 3) : p. 1064-1072.
Neto, C.S.a.A.M.F., Ferrofluids.' Properties andApplications. Brazilian Journal of Physics, 2005. 35( 3a) : p.
718-727.
Popplewell, J., Technologicalapp//cations of ferrof/uids. Physics in Technology, 1984. 15( 3) : p. 150-1 56.
K. Bulter, P.H.B., P. M. Frederik, G. J. Vroege, and A. P. Philipse, D,rect Observation of D,00lar Cha/ns in Ferrofluids in Zero Field Us/ng Cryogenic Electron Microscopy. Journal of Physics Condensed Matter, 2003.
15( 15) : p. S1451-S1470.
Corporation, L. Dr. Da ves Do-It- Yours el! MR Fluid, Designing with MR Fluid, Magnetic Circuit Desígn, FA Os.
2004; Available from: www.lord.com.
Liu, J., et al., Field-Induced Structures in Ferrofiuid Emulsions. Physical Review Letters, 1995. 74( 14) : p.
2828-2831.
E. Lernaire, Y.G.a.G.B., Field induced s(ructure ,n magneto and electro-rheological fiuids. Journal de Physique II, 1992. 2( 3) : p 359-369.
Odenbach, S. and S. Thurm, Magnetoviscous Effects in Ferrofiuids Ferrofiuids, S. Odenbach, Editor 2003, Springer Berlin 1 Heidelberg. p. 185-201.
McTague, J.P., Magnetoviscosity of Magnetic Coioids. The Journal of Chemical Physics, 1969. 51( 1) p.
133-136.
SHLIOMIS, Ml., Effective viscosity of magnetic suspensions. Soviet Phys. JETP, 1974. 36( 6) p. 1291
- 1294.
Carlson, J.D., What Makes a 000d MR Fluid, in 8th International Conference on ER Fluids and MR Flufds Suspensions200 1: N ce.
M.R. Jolly, J.W.B.a.J.D.C., Properties and Applications of Commercial Magnetorheological Flu,ds, in Proceedings of the 5th SPlEAnnuallnt. Symposium on Smart Strucfures and Materialsl 998: San Diego, CA.
Saldivar-Guerrero, R., Obtención de fluidos magneticos y cara cferiza clon de su comportamiento
magneforeologico, 2004, CIQA: Saltillo, Coahuila, Mexico.
Volkova, O., et al., Magnetorheology of magnet/c boles compared to magnetic partidas. Journal of Rheology, 2000.44( 1) :p.91-104.
López-López, MT., et al., Magnetorheology for suspensions of solid particles dispersed in ferrofluids. Journal of Physics: Condensed Matter, 2006. 18( 38) : p. S2803.
Bossis, G., et al., Magnetorheologicaltluids. Journal of Magnetism and Magnetic Materials, 2002. 252( 0) p. 224-228.
Vestal, C.R. and Z.J. Zhang, Effects of Surface Coordination Chemistry on the Magnetic Properties of
MnFe204 Spine/ Ferrita Nanoparticles. Journal of the American Chemical Society, 2003. 125( 32) : p. 9828- 9833.
Hong, X., et al., Periodate oxidation of nanoscaled magnetíc dextran composites. Journal of Magnetism and Magnetic Materials, 2004. 269( 1) : p. 95-100.
Saini, DR., A.V. Shenoy, and V.M. Nadkarni, Dynamic mechanical properfies of highly loaded ferrita-fi/lcd thermoplastic elastomer. Journal of Applied Polymer Science, 1984. 29( 12) : p. 4123-4143.
Wang, M.-J., Effect of Polymer-Fifier and Filler-Filler mtera ctions on Dynamic Properties of Filled Vulcanizates. RubberChemistry and Technology. 1998. 71( 3) : p. 520-589.
Lawrence E Nielsen, N., Robert F Landel, Mechanica/PropertiesofPo/ymers and Composites. 2a ed1993:
CRC.
Anand, J.N., Re: Contact TheoryofAdhesion. The Journal of Adhesion, 1973. 5( 3) : p. 265-267.
Martin, J. E., K.M. Hill, and C.P. Tigges, Magnetic-fie/d-/nducedoptica/transm/ttancein co//oida/suspensions.
Physical Review E, 1999. 59( 5) : p. 5676-5692.
Gallardo, PS., Desarrollo de Materia/es Magnéticos a base de Mezclas de Po//meros y Cargas Minera/es Especia/es, 2001, CIQA: Mexico.
Yáñez-Flores, l.G., et al., Psi-oxide cross/inking of PVC foam formu/ations. European Polymer Journal, 2000.
36( 10) :p. 2235-2241.
Santoyo-Salazar, J., M.A. Castellanos-Roman, and L. Beatriz Gómez, Structura/ and magnetic domains characteriration of magnetite nanopartic/es. Materials Science and Engineering: C, 2007. 27( 5 1 8) : p.
* 1317-1320.
Takahoshi, H., H. Saito, and S. lshio, MFM ana/ysis of magnetizat/on process in CoPt dot-array. Journal of Magnetism and Magnetic Materials, 2004. 272 • 276, Supplement( 0) : p. E1313-E1 31 5.
Aren as-Al atorre, J., el al., Advantages and llmitations of OM, SEM, TEM and AFM in (he study of ancient decoratedpoftery. Applied Physics A: Materials Science & Processing, 2010. 98( 3) : p. 6 17-624.
El-Hilo, M., el al., The effects of different demagnetisation processes on interaction effects in (hin fiim media.
Magnetics, IEEE Transaclions on, 1992. 28( 5) : p. 3282-3284.
O'Grady, K., M. El-Hilo, and R.W. Chantreil, The character/sation of interaction effects in fine particle systems.
Magnetics, IEEE Transactions on, 1993. 29( 6) : p. 2608-2613.
M. R. Jolly, J.D.C.a.C.M., A mode/ of (he behav,our of magnetorheo/ogica/ materia/s Smart Materials and Structures, 1996. 5( 5) : p. 607-614.
J.M. GINDER, L.C.D.a.L.D.E., RHEOLOGY OF MAGNETORHEOLOG/CAL FLU/DS: MODELS AND MEASUREMENTS. International Journal of Modern Physics B ( IJMPB) , 1996. 10( 23-24) : p. 3293-3303.
Rosensweig, R.E., On magnetorheo/ogy and electrorheo/ogy as states of unsymmetric s(ress. Journal of Rheology, 1995. 39( 1) : p. 179-192.
Bossis, G. and E. Lemaire, Yield stresses in magnetic suspensions. Journal of Rheology, 1991. 35( 7) : p.
1345-1 354.
Klingenberg, D.J. and C.F. Zukoski, Studies on (he steady-shear behavior of e/ectrorheo/og/ca/ suspensions.
Langmuir, 1990. 6( 1) : p. 15-24.
Henkel, O., Remanenzverha/ten und Wechse/wirkungen in hartmagnetischen Tei/chenko//ektiven. physica status solidi ( b) , 1964. 7( 3) : p. 919-929.