• No se han encontrado resultados

Logros académicos

In document 1.1 Proceso NMP - Repositorio CIQA (página 179-187)

Capítulo 8: Conclusiones y trabajo a futuro

8.4 Logros académicos

En esta sección se presentan los logros científicos producidos durante el desarrollo del presente estudio doctoral:

 Contreras-López, D., Luna-Bárcena, G., Saldívar-Guerra, E. Eur Polym J 2013, 49 (7), 1760. Copolymerization of isoprene with polar vinyl monomers: Reactivity ratios, characterization and thermal properties.”

 XXVI Congreso Nacional de la Sociedad Polimérica de MéxicoCopolimerización de isopreno con monómeros vinílicos polares: Índices de reactividad.; SPM. 6 – 9 noviembre 2013. Coatzacoalcos, Veracruz, México.

 3ra reunión de la Red de Polímeros/2do simposio de radicálica controlada

Copolímeros de isopreno con monómeros polares vía CRP; CIQA-CIMAV (Mty) 28-31 octubre 2013. Saltillo/Monterrey, México.

Estancia Doctoral en Queen’s University, Kingston, Ontario, Canadá; Enero– Julio 2014.

157

Artículos en escritura:

Copolymerization of isoprene with glycidyl methacrylate: RAFT and NMRP”

Contreras-López, D., Saldívar-Guerra, E.

“PLP-SEC Study of free radical copolymerization of Isoprene and Glycidyl Methacrylate” Contreras-López, D., Saldívar-Guerra, E., Schier, J., Hutchinson, R.

“Synthesis of functional polyamines for use in two-phase partitioning bioreactors (TPPBs)” Peterson, E., Contreras-López, D., Parent, S.

158

Referencias

1. Utracki, L. A., Introduction to polymer blends Polymer Blends Handbook: New York, 2003; Vol. Capítulo 1.

2. Paul, D. R., Polymer Blends. Elsevier Science: 2012.

3. (a) Die Makrom Chem 1967, 101 (1), 58. Riess, V. G., et al., Über die verträglichkeit von copolymeren mit den entsprechenden homopolymeren; (b) Polym Eng Sci 1996, 36 (12), 1574. Ajji, A., et al., Interphase and compatibilization of polymer blends.

4. (a) Majumdar, et al., Polymer Blends. In Encyclopedia of Polymer Science and Technology, Horák, Z., et al., Eds.

John Wiley & Sons, Inc.: 2002; Vol. 1; (b) Datta, S., et al., Polymeric Compatibilizers. Hanser Publishers Münich, 1996; Vol.

Capítulo 1.

5. (a) Polymer 2007, 48 (20), 5960. Hoon Kim, D., et al., Effect of the ratio of maleated polypropylene to organoclay on the structure and properties of TPO-based nanocomposites. Part I: Morphology and mechanical properties; (b) J Appl Polym Sci 2008, 109 (2), 1048. Nguyen, Q. T., et al., Dispersion of nanoclay into polypropylene with carbon dioxide in the presence of maleated polypropylene; (c) Polymer 2008, 49 (10), 2492. Kim, D. H., et al., Effect of the ratio of maleated polypropylene to organoclay on the structure and properties of TPO-based nanocomposites. Part II: Thermal expansion behavior.

6. J Comp Mater 2005, 39 (8), 745. Ahmadi, S. J., et al., Morphology and Characterization of Clay-reinforced EPDM Nanocomposites.

7. (a) Macromolecules 2003, 36 (3), 804. Lee, K. M., et al., Linear Dynamic Viscoelastic Properties of Functionalized Block Copolymer/Organoclay Nanocomposites; (b) Macromolecules 2004, 37 (20), 7649. Choi, S., et al., Effects of Triblock Copolymer Architecture and the Degree of Functionalization on the Organoclay Dispersion and Rheology of Nanocomposites.

8. Horák, Z., et al., Polymer Blends. In Encyclopedia of Polymer Science and Technology, John Wiley & Sons, Inc.:

2002.

9. Polym Adv Tech 2011, 22 (4), 395. Joseph, P., et al., Reactive modifications of some chain- and step-growth polymers with phosphorus-containing compounds: effects on flame retardance—a review.

10. Arrighi, V., et al., Miscibility. In Encyclopedia of Polymer Science and Technology, John Wiley & Sons, Inc.: 2002.

11. (a) J Polym Sci Part B 1995, 33 (12), 1751. González-Montiel, A., et al., Morphology of nylon 6/polypropylene blends compatibilized with maleated polypropylene; (b) Polymer 1995, 36 (24), 4605. González-Montiel, A., et al., Impact-modified nylon 6/polypropylene blends: 2. Effect of reactive functionality on morphology and mechanical properties; (c) Polymer 1995, 36 (24), 4587. González-Montiel, A., et al., Impact-modified nylon 6/polypropylene blends: 1. Morphology-property relationships; (d) Polymer 1995, 36 (24), 4621. González-Montiel, A., et al., Impact-modified nylon 6/polypropylene blends:

3. Deformation mechanisms.

12. Adv Polym Tech 2013, 32 (S1), E399. Mujal-Rosas, R., et al., Dielectric, Thermal, and Mechanical Properties of Acrylonitrile Butadiene Styrene Reinforced with Used Tires.

13. J Appl Polym Sci 1977, 21 (1), 113. Taylor, N. W., et al., Tailoring closely packed gel–particle systems for use as thickening agents.

14. J Appl Polym Sci 2012, 124 (2), 1031. Poh, B. T., et al., Adhesion behavior of natural rubber-based adhesives crosslinked by benzoyl peroxide.

15. (a) J Appl Polym Sci 2003, 88 (2), 266. Raghu, P., et al., Effect of styrene–isoprene–styrene, styrene–butadiene–

styrene, and styrene–butadiene–rubber on the mechanical, thermal, rheological, and morphological properties of polypropylene/polystyrene blends; (b) J Appl Polym Sci 2013, 127 (2), 1164. Ismail, H., et al., Compatibilization of bentonite filled ethylene-propylene-diene monomer composites: Effect of maleic anhydride grafted EPDM; (c) J Appl Polym Sci 2013, 127 (2), 1148. Sadik, T., et al., Polyolefins/Poly(3-hydroxybutyrate-co-hydroxyvalerate) blends compatibilization: Morphology, rheological, and mechanical properties.

16. Macromolecules 1996, 29 (7), 2498. Fischer, M., et al., On the evolution of phase patterns during the high-impact- modified polystyrene process.

17. (a) Macromolecules 2005, 38 (22), 8966. Wang, Z. M., et al., Synthesis of Maleic Anhydride Grafted Polypropylene with High Molecular Weight Using Borane/O2 Radical Initiator and Commercial PP Polymers; (b) Polym Eng Sci 2013, n/a.

Gallego, R., et al., Synthesis of new compatibilizers to poly(lactic acid) blends.

18. J Amer Chem Soc 1956, 78 (11), 2656. Szwarc, M., et al., Polymerization initiated by electron transfer to monomer.

A new method of formation of block polymers.

19. Chem Rev 2009, 109 (11), 5245. Aoshima, S., et al., A Renaissance in Living Cationic Polymerization.

20. Science 1991, 251 (4996), 887. Webster, O. W., Living Polymerization Methods.

159

21. Macromolecules 1989, 22 (4), 1558. Risse, W., et al., A novel route to block copolymers by changing the mechanism from living ring-opening metathesis polymerization of cyclic olefins to aldol condensation polymerization of silyl vinyl ethers.

22. Mater Today 2005, 8 (3), 26. Matyjaszewski, K., et al., Controlled/living radical polymerization.

23. Odian, G., Principles of Polymerization. 4th ed.; Wiley: 2004.

24. Prog Polym Sci 2004, 29 (4), 329. Goto, A., et al., Kinetics of living radical polymerization.

25. (a) Prog Polym Sci 2006, 31 (12), 1068. Hadjichristidis, N., et al., Macromolecular architectures by living and controlled/living polymerizations; (b) Prog Polym Sci 2006, 31 (12), 1041. Smid, J., et al., Perspectives on the contributions of Michael Szwarc to living polymerization; (c) Prog Polym Sci 2007, 32 (2), 173. Baskaran, D., et al., Anionic vinyl polymerization—50 years after Michael Szwarc.

26. Die Makrom Chem, Rap Commun 1982, 3 (2), 127. Otsu, T., et al., Role of initiator-transfer agent-terminator (iniferter) in radical polymerizations: Polymer design by organic disulfides as iniferters.

27. (a) J Polym Sci Part A 2000, 38 (10), 1706. Darling, T. R., et al., Living polymerization: Rationale for uniform terminology; (b) Matyjaszewski, K., et al., Naming of controlled, living and ‘living’ polymerizations, Macromolecular Nomenclature Note 12. Nomenclature Committee of the ACS Division of Polymer Chemistry guest presentation. Disponible en: http://www.polyacs.org/725.html

28. Account Chem Res 2008, 41 (9), 1133. Moad, G., et al., Toward Living Radical Polymerization.

29. (a) Angew Chem Int Ed 2011, 50 (22), 5034. Tebben, L., et al., Nitroxides: Applications in Synthesis and in Polymer Chemistry; (b) Chem Rev 2001, 101 (12), 3661. Hawker, C. J., et al., New Polymer Synthesis by Nitroxide Mediated Living Radical Polymerizations; (c) Polymer Reviews 2011, 51 (2), 104. Grubbs, R. B., Nitroxide-Mediated Radical Polymerization:

Limitations and Versatility; (d) Prog Polym Sci 2013, 38 (1), 63. Nicolas, J., et al., Nitroxide-mediated polymerization.

30. (a) Matyjaszewski, K., Radical Polymerization. In Controlled and Living Polymerizations, Wiley: 2010; pp 103; (b)

Matyjaszewski, K., et al., Handbook of radical polymerization. Wiley-Interscience: 2002.

31. (a) Aust J Chem 2005, 58 (6), 379. Moad, G., et al., Living Radical Polymerization by the RAFT Process; (b) Aust J Chem 2006, 59 (10), 669. Moad, G., et al., Living Radical Polymerization by the RAFT Process—A First Update; (c) Barner- Kowollik, C., Handbook of RAFT Polymerization. Wiley: 2008.

32. Polymer 2008, 49 (5), 1079. Moad, G., et al., Radical addition–fragmentation chemistry in polymer synthesis.

33. Chem Rev 2006, 106 (9), 3936. David, G., et al., Use of Iodocompounds in Radical Polymerization.

34. (a) J Polym Sci Part A 2000, 38 (10), 1753. Gridnev, A., The 25th anniversary of catalytic chain transfer; (b) Chem Rev 2001, 101 (12), 3611. Gridnev, A. A., et al., Catalytic Chain Transfer in Free-Radical Polymerizations.

35. Macromolecules 1994, 27 (3), 638. Greszta, D., et al., "Living" radical polymerization. 1. Possibilities and limitations.

36. J Macrom Sci Part C 2001, 41 (3), 139. Bisht, H. S., et al., Living free-radical polymerization -A review

37. (a) J Molec Model 2010, 16 (1), 95. Rodríguez-Sanchez, I., et al., Theoretical evaluation of the order of reactivity of transfer agents utilized in RAFT polymerization; (b) Can J Chem Eng 2012, 90 (4), 804. Zapata-González, I., et al., Efficient numerical integration of stiff differential equations in polymerisation reaction engineering: Computational aspects and applications; (c) J Macrom Sci Part A 2006, 43 (7), 995. Tuinman, E., et al., Controlled FreeRadical Copolymerization Kinetics of Styrene and Divinylbenzene by Bimolecular NMRP using TEMPO and Dibenzoyl Peroxide; (d) Flores-Tlacuahuac, A., et al., Dynamic modelling, nonlinear parameter fitting and sensitivity analysis of a living free-radical polymerization reactor.

In Computer Aided Chemical Engineering, Asprey, S. P.; Macchietto, S., Eds. Elsevier: 2003; Vol. Volume 16, pp 21; (e) J Macrom Sci Part A 2006, 43 (9), 1293. Pallares, J., et al., A Comparison of Reaction Mechanisms for Reversible Addition Fragmentation Chain Transfer Polymerization Using Modeling Tools.

38. (a) Appl Catal A 2011, 397 (1–2), 225. Barrientos-Ramírez, S., et al., Influence of the surface chemistry of activated carbons on the ATRP catalysis of methyl methacrylate polymerization; (b) Polym Adv Tech 2012, 23 (3), 375. Enríquez- Medrano, F. J., et al., Super impact strength of blends prepared from regular HIPS and poly(butyl acrylate)-block-poly(styrene) obtained by RAFT polymerization; (c) J Appl Polym Sci 2011, 119 (4), 2476. Enríquez-Medrano, F. J., et al., Synthesis of diblock and triblock copolymers from butyl acrylate and styrene by reverse iodine transfer polymerization; (d) Macrom Chem Phys 2013, 214 (12), 1396. García-Valdez, O., et al., Grafting of Chitosan with Styrene and Maleic Anhydride via Nitroxide- Mediated Radical Polymerization in Supercritical Carbon Dioxide; (e) J Mater Sci 2010, 45 (7), 1878. Nogueira, T. R., et al., Nitroxide-mediated radical copolymerization of styrene and divinylbenzene: increased polymerization rate by using TBEC as initiator; (f) Eur Polym J 2010, 46 (2), 298. Bonilla-Cruz, J., et al., Controlled “Grafting-from” of poly[styrene-co-maleic anhydride] onto polydienes using nitroxide chemistry.

39. (a) Polymer 2004, 45 (3), 815. Cuatepotzo-Dı́Az, R., et al., Nitroxide mediated polymerization using diphenyl azabutane N-oxides. A study of electronic effects and of the [nitroxide]/[initiator] ratio on the polymerization control; (b) J Polym Res 2011, 18 (4), 559. Percino, M. J., et al., Atom transfer radical polymerization of monomers containing amide and ester moieties monitored by dilatometric method; (c) Polymer 2009, 50 (21), 5024. Jaramillo-Soto, G., et al., Effect of stabilizer

160

concentration and controller structure and composition on polymerization rate and molecular weight development in RAFT polymerization of styrene in supercritical carbon dioxide.

40. (a) J Amer Chem Soc 1995, 117 (20), 5614. Wang, J.-S., et al., Controlled/"living" radical polymerization. atom transfer radical polymerization in the presence of transition-metal complexes; (b) Macromolecules 1995, 28 (5), 1721. Kato, M., et al., Polymerization of Methyl Methacrylate with the Carbon Tetrachloride/Dichlorotris- (triphenylphosphine)ruthenium(II)/Methylaluminum Bis(2,6-di-tert-butylphenoxide) Initiating System: Possibility of Living Radical Polymerization.

41. (a) Macromolecules 1997, 30 (24), 7631. Lecomte, P., et al., Controlled Radical Polymerization of Methyl Methacrylate in the Presence of Palladium Acetate, Triphenylphosphine, and Carbon Tetrachloride; (b) Macromolecules 1996, 29 (27), 8576. Granel, C., et al., Controlled Radical Polymerization of Methacrylic Monomers in the Presence of a Bis(ortho-chelated) Arylnickel(II) Complex and Different Activated Alkyl Halides; (c) J Organom Chem 1999, 584 (2), 246.

Brandts, J. a. M., et al., Controlled radical polymerization of styrene in the presence of lithium molybdate(V) complexes and benzylic halides; (d) Macromolecules 1999, 32 (8), 2420. Kotani, Y., et al., Re(V)-Mediated Living Radical Polymerization of Styrene:1 ReO2I(PPh3)2/R−I Initiating Systems; (e) Macromolecules 1997, 30 (26), 8161. Matyjaszewski, K., et al., Controlled/“Living” Radical Polymerization of Styrene and Methyl Methacrylate Catalyzed by Iron Complexes1.

42. (a) Chem Rev 2001, 101 (12), 3689. Kamigaito, M., et al., Metal-Catalyzed Living Radical Polymerization; (b)

Macromolecules 1999, 32 (20), 6431. Matyjaszewski, K., et al., An Investigation into the CuX/2,2‘-Bipyridine (X = Br or Cl) Mediated Atom Transfer Radical Polymerization of Acrylonitrile; (c) Macromol Rap Commun 2000, 21 (4), 190. Teodorescu, M., et al., Controlled polymerization of (meth)acrylamides by atom transfer radical polymerization; (d) Chem Commun 1999, (14), 1285. J. Ashford, E., et al., First example of the atom transfer radical polymerisation of an acidic monomer: direct synthesis of methacrylic acid copolymers in aqueous media.

43. (a) Soft Matter 2009, 5 (23), 4788. Gao, C., et al., Facile synthesis and self-assembly of multihetero-arm hyperbranched polymer brushes; (b) Aust J Chem 2009, 62 (10), 1371. Xiong, X. Q., Efficient Synthesis of Dendritic Architectures by One-Pot Double Click Reactions; (c) Biomacromolecules 2008, 9 (11), 3231. Yin, M., et al., Dendritic Star Polymers for Efficient DNA Binding and Stimulus-Dependent DNA Release.

44. Prog Polym Sci 2007, 32 (1), 93. Braunecker, W. A., et al., Controlled/living radical polymerization: Features, developments, and perspectives.

45. (a) Polymer Bulletin 1982, 6 (11-12), 589. Moad, G., et al., A product study of the nitroxide inhibited thermal polymerization of styrene; (b) Macromolecules 1982, 15 (3), 909. Moad, G., et al., Selectivity of the reaction of free radicals with styrene; (c) Die Makrom Chem, Rap Commun 1982, 3 (8), 533. Moad, G., et al., Reactions of benzoyloxyl radicals with some common vinyl monomers.

46. Macromol Symp 1994, 88 (1), 89. Georges, M. K., et al., Breathing new life into the free radical polymerization process.

47. Chem Rev 2001, 101 (12), 3581. Fischer, H., The Persistent Radical Effect:  A Principle for Selective Radical Reactions and Living Radical Polymerizations.

48. (a) J Amer Chem Soc 1994, 116 (24), 11185. Hawker, C. J., Molecular Weight Control by a "Living" Free-Radical Polymerization Process; (b) Account Chem Res 1997, 30 (9), 373. Hawker, C. J., “Living” Free Radical Polymerization:  A Unique Technique for the Preparation of Controlled Macromolecular Architectures; (c) Polym Rev 2011, 51 (2), 104. Grubbs, R. B., Nitroxide-Mediated Radical Polymerization: Limitations and Versatility.

49. Macromolecules 1995, 28 (24), 8453. Odell, P. G., et al., Rate Enhancement of Living Free-Radical Polymerizations by an Organic Acid Salt.

50. Moad, G., et al., The Chemistry of Radical Polymerization. 2nd ed.; Elsevier Science: Oxford, U. K., 2006.

51. J Polym Sci Part A 2007, 45 (23), 5487. Dollin, M., et al., Rapid additive-free TEMPO-mediated stable free radical polymerizations of styrene.

52. (a) Macromolecules 2000, 33 (2), 363. Benoit, D., et al., Accurate Structural Control and Block Formation in the Living Polymerization of 1,3-Dienes by Nitroxide-Mediated Procedures; (b) Macromolecules 1996, 29 (27), 8992. Listigovers, N. A., et al., Narrow-Polydispersity Diblock and Triblock Copolymers of Alkyl Acrylates by a “Living” Stable Free Radical Polymerization; (c) Macromolecules 2000, 33 (4), 1141. Grimaldi, S., et al., Acyclic β-Phosphonylated Nitroxides:  A New Series of Counter-Radicals for “Living”/Controlled Free Radical Polymerization.

53. (a) Tetrahedron 1997, 53 (45), 15225. Malmström, E., et al., Development of a new class of rate-accelerating additives for nitroxide-mediated ‘living’ free radical polymerization; (b) Macromolecules 1998, 31 (21), 7559. Keoshkerian, B., et al., Polyacrylates and Polydienes to High Conversion by a Stable Free Radical Polymerization Process:  Use of Reducing Agents; (c) Macromolecules 2006, 39 (16), 5359. Debuigne, A., et al., Stable Free Radical Polymerization of Acrylates Promoted by α-Hydroxycarbonyl Compounds.

161

54. (a) Macromolecules 1996, 29 (16), 5245. Hawker, C. J., et al., Initiating Systems for Nitroxide-Mediated “Living”

Free Radical Polymerizations:  Synthesis and Evaluation; (b) Solomon, D. H., et al. Polymerization process and polymers produced thereby. US Patent 4581429, 1986.

55. Macromolecules 1998, 31 (16), 5559. Chiefari, J., et al., Living Free-Radical Polymerization by Reversible Addition−Fragmentation Chain Transfer:  The RAFT Process.

56. Macromolecules 1995, 28 (15), 5381. Krstina, J., et al., Narrow Polydispersity Block Copolymers by Free-Radical Polymerization in the Presence of Macromonomers.

57. Polym Intern 2000, 49 (9), 993. Moad, G., et al., Living free radical polymerization with reversible addition – fragmentation chain transfer (the life of RAFT).

58. Polymer 2005, 46 (19), 8483. Drache, M., et al., Modeling RAFT polymerization kinetics via Monte Carlo methods:

cumyl dithiobenzoate mediated methyl acrylate polymerization.

59. (a) Macromolecules 2004, 37 (4), 1219. Kwak, Y., et al., Rate Retardation in Reversible Addition−Fragmentation Chain Transfer (RAFT) Polymerization:  Further Evidence for Cross-Termination Producing 3-Arm Star Chain; (b) Aust J Chem 2002, 55 (7), 425. Vana, P., et al., Recent Advances in the Kinetics of Reversible Addition Fragmentation Chain-Transfer Polymerization.

60. Macromolecules 2001, 34 (3), 349. Monteiro, M. J., et al., Intermediate Radical Termination as the Mechanism for Retardation in Reversible Addition−Fragmentation Chain Transfer Polymerization.

61. Macromolecules 1999, 32 (16), 5457. Hawthorne, D. G., et al., Living Radical Polymerization with Reversible Addition−Fragmentation Chain Transfer (RAFT):  Direct ESR Observation of Intermediate Radicals.

62. (a) Macromolecules 2004, 37 (3), 744. Ah Toy, A., et al., Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization of Methyl Acrylate:  Detailed Structural Investigation via Coupled Size Exclusion Chromatography−Electrospray Ionization Mass Spectrometry (SEC−ESI-MS); (b) Polymer 2005, 46 (19), 8448. Feldermann, A., et al., An in-depth analytical approach to the mechanism of the RAFT process in acrylate free radical polymerizations via coupled size exclusion chromatography–electrospray ionization mass spectrometry (SEC–ESI-MS).

63. J Polym Sci Part A 2006, 44 (20), 5809. Barner-Kowollik, C., et al., Mechanism and kinetics of dithiobenzoate- mediated RAFT polymerization. I. The current situation.

64. (a) Macromol Rap Commun 2012, 33 (15), 1273. Meiser, W., et al., “Assessing the RAFT Equilibrium Constant via Model Systems: An EPR Study”—Response to a Comment; (b) Macromol Rap Commun 2011, 32 (18), 1490. Meiser, W., et al., Assessing the RAFT Equilibrium Constant via Model Systems: An EPR Study.

65. Macromol Rap Commun 2006, 27 (9), 653. Favier, A., et al., Experimental Requirements for an Efficient Control of Free-Radical Polymerizations via the Reversible Addition-Fragmentation Chain Transfer (RAFT) Process.

66. (a) Macromolecules 2003, 36 (7), 2256. Chong, Y. K., et al., Thiocarbonylthio Compounds [SC(Ph)S−R] in Free Radical Polymerization with Reversible Addition-Fragmentation Chain Transfer (RAFT Polymerization). Role of the Free- Radical Leaving Group (R); (b) Macromolecules 2003, 36 (7), 2273. Chiefari, J., et al., Thiocarbonylthio Compounds (SC(Z)S−R) in Free Radical Polymerization with Reversible Addition-Fragmentation Chain Transfer (RAFT Polymerization).

Effect of the Activating Group Z.

67. Chem & Eng News July 2, 2007, 85 (27), 55. Facts & figures of the chemical industry.

68. Peters, E. N., Plastics: Thermoplastics, Thermosets, and Elastomers. In Handbook of Materials Selection, John Wiley

& Sons, Inc.: 2007; pp 335.

69. (a) Polym Eng Sci 2011, 51 (1), 1. Patham, B., et al., Thermoplastic vibration welding: Review of process phenomenology and processing–structure–property interrelationships; (b) J Appl Polym Sci 2013, n/a. Yan, G., et al., Development of lightweight thermoplastic composites based on polycarbonate/acrylonitrile–butadiene–styrene copolymer alloys and recycled carbon fiber: Preparation, morphology, and properties; (c) J Appl Polym Sci 2012, 125 (1), 745. Juntuek, P., et al., Effect of glycidyl methacrylate-grafted natural rubber on physical properties of polylactic acid and natural rubber blends.

70. Datta, S., et al., Polymeric Compatibilizers: Uses and Benefits in Polymer Blends. Carl Hanser Verlag: 1996.

71. (a) J Polym Sci Part A 2006, 44 (9), 2972. Tsuchida, A., et al., Grafting of polymers onto and/or from silica surface during the polymerization of vinyl monomers in the presence of γ-ray-irradiated silica; (b) Eur Polym J 2013, 49 (5), 1007.

Songsing, K., et al., Kinetics and mechanism of grafting styrene onto natural rubber in emulsion polymerization using cumene hydroperoxide–tetraethylenepentamine as redox initiator; (c) Ind Crops & Prod 2013, 46 (0), 191. Panesar, S. S., et al., Functionalization of lignin: Fundamental studies on aqueous graft copolymerization with vinyl acetate.

72. Xanthos, M., Reactive Extrusion: Principles and Practice, Chapter 2 "Process analysis from reaction fundamentals:

Examples of polymerization and controlled degradation in extruders". Hanser Publishers: 1992.

162

73. (a) Prog Polym Sci 1999, 24 (1), 81. Moad, G., The synthesis of polyolefin graft copolymers by reactive extrusion; (b) Prog Polym Sci 2002, 27 (6), 1007. Russell, K. E., Free radical graft polymerization and copolymerization at higher temperatures.

74. Chem Rev 1973, 73 (5), 441. Gibian, M. J., et al., Organic radical-radical reactions. Disproportionation vs.

combination.

75. Polym Eng Sci 2006, 46 (12), 1754. Parent, J. S., et al., Radical mediated graft modification of polyolefins:

Vinyltriethoxysilane addition dynamics and yields.

76. (a) Macromol Rap Commun 2007, 28 (13), 1397. Bonilla-Cruz, J., et al., Towards Controlled Graft Polymerization of Poly[styrene-co-(maleic anhydride)] on Functionalized Silica Mediated by Oxoaminium Bromide Salt. Facile Synthetic Pathway Using Nitroxide Chemistry; (b) Macrom Chem Phys 2008, 209 (21), 2268. Bonilla-Cruz, J., et al., Controlled Grafting-From of Polystyrene on Polybutadiene: Mechanism and Spectroscopic Evidence of the Functionalization of Polybutadiene with 4-Oxo-TEMPO; (c) Macromol Symp 2009, 283–284 (1), 110. Saldívar-Guerra, E., et al., Progress in Controlled Grafting-From by Nitroxide Chemistry.

77. (a) J Appl Polym Sci 1994, 54 (3), 339. Majumdar, B., et al., Effect of extruder type on the properties and morphology of reactive blends based on polyamides; (b) J Appl Polym Sci 1998, 69 (13), 2625. Radonjič, G., et al., Compatibilization of polypropylene/polystyrene blends with poly(styrene-b-butadiene-b-styrene) block copolymer.

78. Polymer 1994, 35 (7), 1552. Favis, B. D., Phase size/interface relationships in polymer blends: the emulsification curve.

79. Eur Polym J 1994, 30 (5), 597. Hlavatá, D., et al., Waxs and saxs investigation of polypropylene crystalline phase in blends with high-impact polystyrene and compatibilizers.

80. J Macrom Sci Part C 2000, 40 (2-3), 167. Schellekens, M. a. J., et al., Synthesis of Polyolefin Block and Graft Copolymers.

81. J Amer Chem Soc 1944, 66 (9), 1594. Mayo, F. R., et al., Copolymerization. I. A Basis for Comparing the Behavior of Monomers in Copolymerization; The Copolymerization of Styrene and Methyl Methacrylate.

82. Hagiopol, C., Copolymerization. Toward a systematic approach. Kluwer Academic/Plenum Publisher: New York, 1999.

83. Chem Rev 1950, 46 (2), 191. Mayo, F. R., et al., Copolymerization.

84. Macromolecules 1993, 26 (19), 5249. Kathmann, E. E. L., et al., Water-soluble copolymers. 48. Reactivity ratios of N-vinylformamide with acrylamide, sodium acrylate, and n-butyl acrylate.

85. (a) J Polym Sci 1950, 5 (2), 259. Finemann, M., et al., Linear method for determining monomer reactivity ratios in copolymerization; (b) J Macrom Sci Part A 1975, 9 (1), 1 Kelen, T., et al., Analysis of the Linear Methods for Determining Copolymerization Reactivity Ratios. I. A New Improved Linear Graphic Method; (c) J Macrom Sci Part A 1976, 10 (8), 1513 Tüdos, F., et al., Analysis of Linear Methods for Determining Copolymerization Reactivity Ratios. III. Linear Graphic Method for Evaluating Data Obtained at High Conversion Levels.

86. (a) J Polym Sci Part A 1965, 3 (1), 369. Tidwell, P. W., et al., An improved method of calculating copolymerization reactivity ratios; (b) J Royal Stat Soc. Serie C 1993, 42 (4), 693. Park M. Reilly, et al., Algorithm AS 286: Parameter Estimation in the Error-in-Variables Model.

87. Brandrup, J., et al., Polymer Handbook. 4th ed.; John Wiley & Sons, Inc.: N. Y., USA, 1999.

88. (a) Eur Polym J 1989, 25 (7–8), 635. Olaj, O. F., et al., Laser-flash-initiated polymerization as a tool for evaluating (individual) kinetic constants of free-radical polymerization—5. Complete analysis by means of a single experiment; (b)

Macromolecules 2002, 35 (25), 9300. Beuermann, S., Requirements Associated with Studies into a Chain-Length Dependence of Propagation Rate Coefficients via PLP−SEC Experiments; (c) Macromolecules 2008, 41 (23), 9011. Wang, W., et al., PLP/SEC/NMR Study of Free Radical Copolymerization of Styrene and Glycidyl Methacrylate; (d) Prog Polym Sci 2002, 27 (2), 191. Beuermann, S., et al., Rate coefficients of free-radical polymerization deduced from pulsed laser experiments.

89. (a) Biomaterials 2001, 22 (17), 2411. Nazhat, S. N., et al., Isoprene-styrene copolymer elastomer and tetrahydrofurfuryl methacrylate mixtures for soft prosthetic applications; (b) J Appl Polym Sci 2003, 88 (4), 921.

Wootthikanokkhan, J., et al., Compatibilization efficacy of poly(isoprene–butyl acrylate) block copolymers in natural/acrylic rubber blends.

90. (a) ACS Nano 2011, 5 (2), 1513. Arias, J. L., et al., Squalene Based Nanocomposites: A New Platform for the Design of Multifunctional Pharmaceutical Theragnostics; (b) Molecular Pharmaceutics 2009, 6 (5), 1526. Reddy, L. H., et al., Anticancer Efficacy of Squalenoyl Gemcitabine Nanomedicine on 60 Human Tumor Cell Panel and on Experimental Tumor; (c) Nano Letters 2006, 6 (11), 2544. Couvreur, P., et al., Squalenoyl Nanomedicines as Potential Therapeutics.

91. (a) Macromolecules 1999, 32 (8), 2806. Schöps, M., et al., Salt-Induced Switching of Microdomain Morphology of Ionically Functionalized Diblock Copolymers; (b) Macromolecules 1999, 32 (9), 3017. Sen, T. Z., et al., Local Dynamics of cis-1,4-Polybutadiene and cis-1,4-Polyisoprene. A Comparative Study Based on Cooperative Kinematics Theory and NMR

In document 1.1 Proceso NMP - Repositorio CIQA (página 179-187)